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Controlling the Coordination Mode of 1,4,7-Triazacyclononane Complexes of Rhodium and Iridium and Evaluating Their Behavior as Phenylacetylene Polymerization Catalysts
A number of κ1- and κ3-triazacyclononane RhI, Ir1, RhIII, and IrIII derivatives have been synthesized and characterized, with conversion from κ1-triazacyclononane complexes to κ3-derivatives. The results of the catalytic studies show that the Rh(I) and Ir(I) complexes polymerize phenylacetylene more...
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Published in: | Organometallics 2008-06, Vol.27 (12), p.2852-2860 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A number of κ1- and κ3-triazacyclononane RhI, Ir1, RhIII, and IrIII derivatives have been synthesized and characterized, with conversion from κ1-triazacyclononane complexes to κ3-derivatives. The results of the catalytic studies show that the Rh(I) and Ir(I) complexes polymerize phenylacetylene more effectively than [M(COD)(μ-Cl)]2 (M = Rh and Ir). |
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ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/om800180a |