Chiral Ligands to Support Self-Assembly of [LPdCl]3 Trimers via a Set of Secondary Interactions

Novel [LPdCl]3 trimers (L = chiral secondary benzylamine) were synthesized via direct cyclopalladation. The structures of trimeric palladacycles were confirmed by means of X-ray analysis. The secondary interactions stabilizing trimeric molecules were investigated. An equilibrium between dimeric and...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics 2009-02, Vol.28 (4), p.1027-1031
Main Authors: Vatsadze, Sergey Z, Medved’ko, Alexey V, Zyk, Nikolay V, Maximov, Anton L, Kurzeev, Sergey A, Kazankov, Gregory M, Lyssenko, Konstantin A
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Novel [LPdCl]3 trimers (L = chiral secondary benzylamine) were synthesized via direct cyclopalladation. The structures of trimeric palladacycles were confirmed by means of X-ray analysis. The secondary interactions stabilizing trimeric molecules were investigated. An equilibrium between dimeric and trimeric palladacycle species was found in solution by means of dynamic NMR- spectroscopy and ESI mass spectrometry study.
ISSN:0276-7333
1520-6041
DOI:10.1021/om8006695