Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes

Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of CO bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves CO insertion into a nickel−hydrogen bond, followed by cleavage of the newly formed Ni−O bond with a silane.

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Published in:Organometallics 2009-01, Vol.28 (2), p.582-586
Main Authors: Chakraborty, Sumit, Krause, Jeanette A, Guan, Hairong
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Language:English
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description Nickel PCP-pincer hydride complexes catalyze chemoselective hydrosilylation of CO bonds of aldehydes and ketones in the presence of other functional groups. The mechanism involves CO insertion into a nickel−hydrogen bond, followed by cleavage of the newly formed Ni−O bond with a silane.
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title Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes
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