On the Nature of the Formation of [(η5-Ind)Ru(CO)2H]: Evidence of a Water-Gas Shift Reaction Mechanism via Triethylamine Reduction

The formation of [(η5-Ind)Ru(CO)2H] from [(η5-Ind)Ru(CO)3]+ was investigated using both 1H and 2H NMR spectroscopy and GC−mass spectrometry. Both NMR and GC-MS data support a water-gas shift reaction mechanism as the cause for formation of [(η5-Ind)Ru(CO)2H].

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Bibliographic Details
Published in:Organometallics 2010-03, Vol.29 (5), p.1061-1063
Main Authors: Badger, Robert C, D’Acchioli, Jason S, Oudenhoven, Tracey A, Walder, Brennan J
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:The formation of [(η5-Ind)Ru(CO)2H] from [(η5-Ind)Ru(CO)3]+ was investigated using both 1H and 2H NMR spectroscopy and GC−mass spectrometry. Both NMR and GC-MS data support a water-gas shift reaction mechanism as the cause for formation of [(η5-Ind)Ru(CO)2H].
ISSN:0276-7333
1520-6041
DOI:10.1021/om9010774