Synthesis and Characterization of Platina-β-diketones

Hexachloroplatinic acid reacts with n-butanol to give the but-2-ene complex H[PtCl3(η2-C4H8)] (3) as intermediate, which reacts with trimethylsilyl-substituted acetylenes R‘C⋮CSiMe3 (R‘ = H, Me, SiMe3) with cleavage of the silyl groups to form platina-β-diketones [Pt2(μ-Cl)2{(COR)2H}2] [R = Me (2a),...

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Published in:Organometallics 1996-05, Vol.15 (10), p.2454-2457
Main Authors: Steinborn, Dirk, Gerisch, Michael, Merzweiler, Kurt, Schenzel, Karla, Pelz, Karsten, Bögel, Horst, Magull, Jörg
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cited_by cdi_FETCH-LOGICAL-a295t-3558fa58a82b168ca5f2541e81717c9d311c007a29b0ccde6b5b952542ad27333
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container_issue 10
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creator Steinborn, Dirk
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Schenzel, Karla
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Magull, Jörg
description Hexachloroplatinic acid reacts with n-butanol to give the but-2-ene complex H[PtCl3(η2-C4H8)] (3) as intermediate, which reacts with trimethylsilyl-substituted acetylenes R‘C⋮CSiMe3 (R‘ = H, Me, SiMe3) with cleavage of the silyl groups to form platina-β-diketones [Pt2(μ-Cl)2{(COR)2H}2] [R = Me (2a), Et (2b)]. The constitution of 2 was determined by microanalysis, NMR (1H, 13C) spectroscopy, IR, Raman, and mass spectroscopy. The structure of 2a was determined by X-ray diffraction.
doi_str_mv 10.1021/om950963k
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title Synthesis and Characterization of Platina-β-diketones
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