Loading…
Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts
Alkyl abstraction from {Me3SiN(CH2CH2NSiMe3)2}ZrR2 (N3ZrR2; R = CH2Ph, Me) using B(C6F5)3 affords cationic alkyl complexes stabilized by a diamide ligand. The ionic η2-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH2B(C6F5)3]- anion; the methyl...
Saved in:
| Published in: | Organometallics 1996-06, Vol.15 (12), p.2672-2674 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83 |
|---|---|
| cites | cdi_FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83 |
| container_end_page | 2674 |
| container_issue | 12 |
| container_start_page | 2672 |
| container_title | Organometallics |
| container_volume | 15 |
| creator | Horton, Andrew D de With, Jan van der Linden, Arjan J van de Weg, Henk |
| description | Alkyl abstraction from {Me3SiN(CH2CH2NSiMe3)2}ZrR2 (N3ZrR2; R = CH2Ph, Me) using B(C6F5)3 affords cationic alkyl complexes stabilized by a diamide ligand. The ionic η2-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH2B(C6F5)3]- anion; the methyl cation coordinates the anion [MeB(C6F5)3]- via a Zr···Me−B interaction. The complexes exhibit moderate ethene polymerization activity. |
| doi_str_mv | 10.1021/om960073k |
| format | article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1021_om960073k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_TPS_93429N6X_5</sourcerecordid><originalsourceid>FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83</originalsourceid><addsrcrecordid>eNptkL1OwzAUhS0EEqUw8AZeGBgCdpw4Dlspv1JVKpGBzbLjG-Q2P5WdiqYTK6_Jk5BS1Inp6kifvqN7EDqn5IqSkF43VcoJSdjiAA1oHJKAk4geogEJEx4kjLFjdOL9nBDCExYOUD1WrW1qm-NRuejKjXV5n1YVHjfVsoQ1eHyrPBjc1FjhzFkDdatawHdWVX3AE_uuanPz_fmFp_CxtUANeNaUXQXObn7tuC9RZedbf4qOClV6OPu7Q5Q93Gfjp2Dy8vg8Hk0CxThtA0gTkdNYcOBKERIaDTyPjEm1jsJcGK2pEkJRKAwRWicsj3VRUBAiJaYQbIgud9rcNd47KOTS2Uq5TlIitzvJ_U49G-xY61tY70HlFrKfKIllNnuVKYvCdMrfZNzzFzte5V7Om5Wr-0f-8f4ANGR5dw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)</source><creator>Horton, Andrew D ; de With, Jan ; van der Linden, Arjan J ; van de Weg, Henk</creator><creatorcontrib>Horton, Andrew D ; de With, Jan ; van der Linden, Arjan J ; van de Weg, Henk</creatorcontrib><description>Alkyl abstraction from {Me3SiN(CH2CH2NSiMe3)2}ZrR2 (N3ZrR2; R = CH2Ph, Me) using B(C6F5)3 affords cationic alkyl complexes stabilized by a diamide ligand. The ionic η2-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH2B(C6F5)3]- anion; the methyl cation coordinates the anion [MeB(C6F5)3]- via a Zr···Me−B interaction. The complexes exhibit moderate ethene polymerization activity.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om960073k</identifier><language>eng</language><publisher>American Chemical Society</publisher><ispartof>Organometallics, 1996-06, Vol.15 (12), p.2672-2674</ispartof><rights>Copyright © 1996 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83</citedby><cites>FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Horton, Andrew D</creatorcontrib><creatorcontrib>de With, Jan</creatorcontrib><creatorcontrib>van der Linden, Arjan J</creatorcontrib><creatorcontrib>van de Weg, Henk</creatorcontrib><title>Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>Alkyl abstraction from {Me3SiN(CH2CH2NSiMe3)2}ZrR2 (N3ZrR2; R = CH2Ph, Me) using B(C6F5)3 affords cationic alkyl complexes stabilized by a diamide ligand. The ionic η2-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH2B(C6F5)3]- anion; the methyl cation coordinates the anion [MeB(C6F5)3]- via a Zr···Me−B interaction. The complexes exhibit moderate ethene polymerization activity.</description><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1996</creationdate><recordtype>article</recordtype><recordid>eNptkL1OwzAUhS0EEqUw8AZeGBgCdpw4Dlspv1JVKpGBzbLjG-Q2P5WdiqYTK6_Jk5BS1Inp6kifvqN7EDqn5IqSkF43VcoJSdjiAA1oHJKAk4geogEJEx4kjLFjdOL9nBDCExYOUD1WrW1qm-NRuejKjXV5n1YVHjfVsoQ1eHyrPBjc1FjhzFkDdatawHdWVX3AE_uuanPz_fmFp_CxtUANeNaUXQXObn7tuC9RZedbf4qOClV6OPu7Q5Q93Gfjp2Dy8vg8Hk0CxThtA0gTkdNYcOBKERIaDTyPjEm1jsJcGK2pEkJRKAwRWicsj3VRUBAiJaYQbIgud9rcNd47KOTS2Uq5TlIitzvJ_U49G-xY61tY70HlFrKfKIllNnuVKYvCdMrfZNzzFzte5V7Om5Wr-0f-8f4ANGR5dw</recordid><startdate>19960611</startdate><enddate>19960611</enddate><creator>Horton, Andrew D</creator><creator>de With, Jan</creator><creator>van der Linden, Arjan J</creator><creator>van de Weg, Henk</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19960611</creationdate><title>Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts</title><author>Horton, Andrew D ; de With, Jan ; van der Linden, Arjan J ; van de Weg, Henk</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1996</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Horton, Andrew D</creatorcontrib><creatorcontrib>de With, Jan</creatorcontrib><creatorcontrib>van der Linden, Arjan J</creatorcontrib><creatorcontrib>van de Weg, Henk</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Horton, Andrew D</au><au>de With, Jan</au><au>van der Linden, Arjan J</au><au>van de Weg, Henk</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1996-06-11</date><risdate>1996</risdate><volume>15</volume><issue>12</issue><spage>2672</spage><epage>2674</epage><pages>2672-2674</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><abstract>Alkyl abstraction from {Me3SiN(CH2CH2NSiMe3)2}ZrR2 (N3ZrR2; R = CH2Ph, Me) using B(C6F5)3 affords cationic alkyl complexes stabilized by a diamide ligand. The ionic η2-benzyl adduct decomposes slowly to give a cationic cyclometalation product, which coordinates the [PhCH2B(C6F5)3]- anion; the methyl cation coordinates the anion [MeB(C6F5)3]- via a Zr···Me−B interaction. The complexes exhibit moderate ethene polymerization activity.</abstract><pub>American Chemical Society</pub><doi>10.1021/om960073k</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 1996-06, Vol.15 (12), p.2672-2674 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_crossref_primary_10_1021_om960073k |
| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| title | Cationic Alkylzirconium Complexes Based on a Tridentate Diamide Ligand: New Alkene Polymerization Catalysts |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T13%3A03%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Cationic%20Alkylzirconium%20Complexes%20Based%20on%20a%20Tridentate%20Diamide%20Ligand:%E2%80%89%20New%20Alkene%20Polymerization%20Catalysts&rft.jtitle=Organometallics&rft.au=Horton,%20Andrew%20D&rft.date=1996-06-11&rft.volume=15&rft.issue=12&rft.spage=2672&rft.epage=2674&rft.pages=2672-2674&rft.issn=0276-7333&rft.eissn=1520-6041&rft_id=info:doi/10.1021/om960073k&rft_dat=%3Cistex_cross%3Eark_67375_TPS_93429N6X_5%3C/istex_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a361t-e978c1586e6aa002dbe6c4dd9bb42c8dbb1a88a1efd08bb73c5bff1e8890df83%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |