Syntheses of Dinuclear Rhenium Complexes with Disulfido and Sulfido Ligands

New dinuclear cyclopentadienylrhenium derivatives with four bridging sulfur ligands have been synthesized and characterized. The disulfide ligands in [Cp‘Re(μ-S2)]2Cl2 have been found to react with dihydrogen, acetylene, and ethene under mild conditions.

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Bibliographic Details
Published in:Organometallics 1997-02, Vol.16 (3), p.294-296
Main Authors: Rakowski DuBois, M, Jagirdar, Balaji R, Dietz, S, Noll, B. C
Format: Article
Language:English
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Description
Summary:New dinuclear cyclopentadienylrhenium derivatives with four bridging sulfur ligands have been synthesized and characterized. The disulfide ligands in [Cp‘Re(μ-S2)]2Cl2 have been found to react with dihydrogen, acetylene, and ethene under mild conditions.
ISSN:0276-7333
1520-6041
DOI:10.1021/om9608972