Synthesis of Luminescent Trinuclear Silver(I) Acetylides of Bis(diphenylphosphino)methane and Bis(diphenylphosphino)-n-propylamine. X-ray Crystal Structures of [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)]2+ and [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)2]

A series of soluble trinuclear silver(I) complexes containing monocapped and bicapped acetylides, [Ag3(LL)3(μ3-η1-C⋮CR)]2+ and [Ag3(LL)3(μ3-η1-C⋮C-C6H4-NO2-p)2]+ [LL=[(C6H5)2P]2CH2 (dppm), [(C6H5)2P]2N n Pr ( n PrPNP)], have been synthesized. The X-ray crystal structures of [Ag3(μ-dppm)3(μ3-η1-C⋮C-C...

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Bibliographic Details
Published in:Organometallics 1997-05, Vol.16 (10), p.2032-2037
Main Authors: Yam, Vivian Wing-Wah, Fung, Wendy Kit-Mai, Cheung, Kung-Kai
Format: Article
Language:English
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Summary:A series of soluble trinuclear silver(I) complexes containing monocapped and bicapped acetylides, [Ag3(LL)3(μ3-η1-C⋮CR)]2+ and [Ag3(LL)3(μ3-η1-C⋮C-C6H4-NO2-p)2]+ [LL=[(C6H5)2P]2CH2 (dppm), [(C6H5)2P]2N n Pr ( n PrPNP)], have been synthesized. The X-ray crystal structures of [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)]2+ and [Ag3(μ-dppm)3(μ3-η1-C⋮C-C6H4-NO2-p)2]+ have been determined.
ISSN:0276-7333
1520-6041
DOI:10.1021/om9609170