Activation of the (Trimethylsilyl)tetramethylcyclopentadienyl Ligand in the [C 5 Me 4 (SiMe 3 )] 2 TiCl 2 /Mg System, Yielding Intramolecular Si−CH 2 −Mg and Si−CH 2 −Ti Bonds. Molecular Structures of {[η 5 -C 5 Me 4 SiMe 2 (μ-CH 2 { Mg , Mg })][η 5 -C 5 Me 4 (SiMe 3 )]Ti III (μ-H) 2 Mg(THF)} 2 and [η 5 :η 1 -C 5 Me 4 SiMe 2 CH 2 ][η 5 -C 5 Me 4 (SiMe 3 )]Ti III

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Published in:Organometallics 1997-09, Vol.16 (19), p.4185-4191
Main Authors: Horáček, Michal, Hiller, Jörg, Thewalt, Ulf, Polášek, Miroslav, Mach, Karel
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Language:English
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cited_by cdi_FETCH-LOGICAL-c743-98c3f322bd79c6780d8d8709a8db39dc316743a5f11184fd0b59ed7131157ecd3
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creator Horáček, Michal
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doi_str_mv 10.1021/om9701783
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title Activation of the (Trimethylsilyl)tetramethylcyclopentadienyl Ligand in the [C 5 Me 4 (SiMe 3 )] 2 TiCl 2 /Mg System, Yielding Intramolecular Si−CH 2 −Mg and Si−CH 2 −Ti Bonds. Molecular Structures of {[η 5 -C 5 Me 4 SiMe 2 (μ-CH 2 { Mg , Mg })][η 5 -C 5 Me 4 (SiMe 3 )]Ti III (μ-H) 2 Mg(THF)} 2 and [η 5 :η 1 -C 5 Me 4 SiMe 2 CH 2 ][η 5 -C 5 Me 4 (SiMe 3 )]Ti III
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