Heterometallic Borole Complexes of Iron and Gold

The first heterometallic borole complexes of Fe and Au have been prepared by reaction of [HFe{η5-(1-phenylborole)}(CO)2]- (1) with [AuCl(PPh3)] in CH2Cl2, and the crystal structure of [(OC)2{η5-(1-phenylborole)}Fe{Au(PPh3)}2] (2) reveals an interesting orientation of the borole ligand. This complex...

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Published in:Organometallics 1998-05, Vol.17 (11), p.2177-2182
Main Authors: Braunstein, Pierre, Herberich, Gerhard E., Neuschütz, Mark, Schmidt, Martin U., Englert, Ulli, Lecante, Pierre, Mosset, Alain
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cited_by cdi_FETCH-LOGICAL-a361t-9e7e0bd968b94b1100c3478628d0c22cf498afe1a2a3308521de3d9f37271063
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creator Braunstein, Pierre
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description The first heterometallic borole complexes of Fe and Au have been prepared by reaction of [HFe{η5-(1-phenylborole)}(CO)2]- (1) with [AuCl(PPh3)] in CH2Cl2, and the crystal structure of [(OC)2{η5-(1-phenylborole)}Fe{Au(PPh3)}2] (2) reveals an interesting orientation of the borole ligand. This complex reacts with [AuCl(PPh3)]/TIPF6 in CH2Cl2 to give the new cationic FeAu3 cluster [(OC)2{η5-(1-phenylborole)}Fe{Au(PPh3)}3]PF6 (4) which has a tetrahedral metal core, as established by a wide angle X-ray scattering study.
doi_str_mv 10.1021/om9703189
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title Heterometallic Borole Complexes of Iron and Gold
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