Synthesis and Structure Determination of the Linear Conjugated Polyynyl and Polyynediyl Iron Complexes Fp−(C⋮C) n −X (X = H (n = 1, 2); X = Fp (n = 1, 2, 4); Fp = (η5-C5Me5)Fe(CO)2)1

A series of polyynyl and polyynediyl complexes of iron, Fp*−(C⋮C) n −H [n = 2 (3)) and Fp*−(C⋮C) n −Fp* (n = 2 (4), 4 (5); Fp* = (η5-C5Me5)Fe(CO)2), have been prepared, and their linear structure has been confirmed by X-ray crystallography.

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Bibliographic Details
Published in:Organometallics 1997-10, Vol.16 (22), p.4882-4888
Main Authors: Akita, Munetaka, Chung, Min-Chul, Sakurai, Aizoh, Sugimoto, Shuichiro, Terada, Masako, Tanaka, Masako, Moro-oka, Yoshihiko
Format: Article
Language:English
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Summary:A series of polyynyl and polyynediyl complexes of iron, Fp*−(C⋮C) n −H [n = 2 (3)) and Fp*−(C⋮C) n −Fp* (n = 2 (4), 4 (5); Fp* = (η5-C5Me5)Fe(CO)2), have been prepared, and their linear structure has been confirmed by X-ray crystallography.
ISSN:0276-7333
1520-6041
DOI:10.1021/om970538m