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Pyrophosphato-Complexes of Nickel and Cobalt in Solution
THE literature on complex pyrophosphates of nickel and cobalt does not record any detailed study of their solutions. Rosenheim 1 observed that from solutions of alkali pyrophosphates containing nickel and cobalt pyrophosphates, the normal pyrophosphates separate unchanged. Later, Bassett and his co-...
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| Published in: | Nature (London) 1950-01, Vol.166 (4226), p.744-745 |
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| container_title | Nature (London) |
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| creator | HALDAR, B. C. |
| description | THE literature on complex pyrophosphates of nickel and cobalt does not record any detailed study of their solutions. Rosenheim
1
observed that from solutions of alkali pyrophosphates containing nickel and cobalt pyrophosphates, the normal pyrophosphates separate unchanged. Later, Bassett and his co-workers
2
stated that nickel and cobalt pyrophosphates dissolve in excess of alkali pyrophosphates giving yellowish-green and purple solutions respectively, but they could not isolate any complex salt in the solid phase. This, however, does not show the non-existence of complex ions containing nickel or cobalt and pyrophosphate ion in solution. I have investigated complex formation in solution by different physico-chemical methods such as thermometric, transport, conductometric,
p
H measurements, cryoscopy in saturated sodium sulphate solutions and magnetic measurements. |
| doi_str_mv | 10.1038/166744a0 |
| format | article |
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1
observed that from solutions of alkali pyrophosphates containing nickel and cobalt pyrophosphates, the normal pyrophosphates separate unchanged. Later, Bassett and his co-workers
2
stated that nickel and cobalt pyrophosphates dissolve in excess of alkali pyrophosphates giving yellowish-green and purple solutions respectively, but they could not isolate any complex salt in the solid phase. This, however, does not show the non-existence of complex ions containing nickel or cobalt and pyrophosphate ion in solution. I have investigated complex formation in solution by different physico-chemical methods such as thermometric, transport, conductometric,
p
H measurements, cryoscopy in saturated sodium sulphate solutions and magnetic measurements.</description><identifier>ISSN: 0028-0836</identifier><identifier>EISSN: 1476-4687</identifier><identifier>DOI: 10.1038/166744a0</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>Humanities and Social Sciences ; letter ; multidisciplinary ; Science ; Science (multidisciplinary)</subject><ispartof>Nature (London), 1950-01, Vol.166 (4226), p.744-745</ispartof><rights>Springer Nature Limited 1950</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c261t-7385317c53fbd3d8073db17a420a53baf3a01dc3a5c344ba5cc355038b8180b03</citedby><cites>FETCH-LOGICAL-c261t-7385317c53fbd3d8073db17a420a53baf3a01dc3a5c344ba5cc355038b8180b03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>HALDAR, B. C.</creatorcontrib><title>Pyrophosphato-Complexes of Nickel and Cobalt in Solution</title><title>Nature (London)</title><addtitle>Nature</addtitle><description>THE literature on complex pyrophosphates of nickel and cobalt does not record any detailed study of their solutions. Rosenheim
1
observed that from solutions of alkali pyrophosphates containing nickel and cobalt pyrophosphates, the normal pyrophosphates separate unchanged. Later, Bassett and his co-workers
2
stated that nickel and cobalt pyrophosphates dissolve in excess of alkali pyrophosphates giving yellowish-green and purple solutions respectively, but they could not isolate any complex salt in the solid phase. This, however, does not show the non-existence of complex ions containing nickel or cobalt and pyrophosphate ion in solution. I have investigated complex formation in solution by different physico-chemical methods such as thermometric, transport, conductometric,
p
H measurements, cryoscopy in saturated sodium sulphate solutions and magnetic measurements.</description><subject>Humanities and Social Sciences</subject><subject>letter</subject><subject>multidisciplinary</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><issn>0028-0836</issn><issn>1476-4687</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1950</creationdate><recordtype>article</recordtype><recordid>eNplj81KxDAYRYMoWEfBR8hSF9Ev_fK3leIfDCqo65KkqdOx05SkA87bWxlduTqbw-UeQs45XHFAc82V0kJYOCAFF1oxoYw-JAVAaRgYVMfkJOc1AEiuRUHMyy7FcRXzuLJTZFXcjH34CpnGlj51_jP01A4NraKz_US7gb7Gfjt1cTglR63tczj75YK8392-VQ9s-Xz_WN0smS8Vn5hGI5FrL7F1DTYGNDaOaytKsBKdbdECbzxa6VEIN8OjlHOIM9yAA1yQi_2uTzHnFNp6TN3Gpl3Nof4prv-KZ_Vyr-ZZGT5Cqtdxm4b53X_3G1c5VKE</recordid><startdate>19500101</startdate><enddate>19500101</enddate><creator>HALDAR, B. C.</creator><general>Nature Publishing Group UK</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19500101</creationdate><title>Pyrophosphato-Complexes of Nickel and Cobalt in Solution</title><author>HALDAR, B. C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c261t-7385317c53fbd3d8073db17a420a53baf3a01dc3a5c344ba5cc355038b8180b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1950</creationdate><topic>Humanities and Social Sciences</topic><topic>letter</topic><topic>multidisciplinary</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HALDAR, B. C.</creatorcontrib><collection>CrossRef</collection><jtitle>Nature (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HALDAR, B. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pyrophosphato-Complexes of Nickel and Cobalt in Solution</atitle><jtitle>Nature (London)</jtitle><stitle>Nature</stitle><date>1950-01-01</date><risdate>1950</risdate><volume>166</volume><issue>4226</issue><spage>744</spage><epage>745</epage><pages>744-745</pages><issn>0028-0836</issn><eissn>1476-4687</eissn><abstract>THE literature on complex pyrophosphates of nickel and cobalt does not record any detailed study of their solutions. Rosenheim
1
observed that from solutions of alkali pyrophosphates containing nickel and cobalt pyrophosphates, the normal pyrophosphates separate unchanged. Later, Bassett and his co-workers
2
stated that nickel and cobalt pyrophosphates dissolve in excess of alkali pyrophosphates giving yellowish-green and purple solutions respectively, but they could not isolate any complex salt in the solid phase. This, however, does not show the non-existence of complex ions containing nickel or cobalt and pyrophosphate ion in solution. I have investigated complex formation in solution by different physico-chemical methods such as thermometric, transport, conductometric,
p
H measurements, cryoscopy in saturated sodium sulphate solutions and magnetic measurements.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><doi>10.1038/166744a0</doi><tpages>2</tpages></addata></record> |
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| ispartof | Nature (London), 1950-01, Vol.166 (4226), p.744-745 |
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| language | eng |
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| source | Nature Journals Online |
| subjects | Humanities and Social Sciences letter multidisciplinary Science Science (multidisciplinary) |
| title | Pyrophosphato-Complexes of Nickel and Cobalt in Solution |
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