Stress relaxation and improved fracture toughness of metal bonding using flexible monolith sheets and an epoxy adhesive

• Published in: Polymer journal 2024-10
• Main Authors: Kamo, Yoshiyuki, Matsumoto, Akikazu
• Format: Article
• Language: English
• ISSN: 0032-3896; 1349-0540
• DOI: 10.1038/s41428-024-00975-w

While epoxy resins exhibit excellent mechanical and insulating properties as well as excellent stability against heat and chemicals, epoxy adhesives also have drawbacks such as brittleness and stress concentration. Rubber-based materials are often added to epoxy adhesives to increase toughness, but they are sensitive to heat and moisture, limiting their effectiveness in harsh environments. In this study, we propose a new sheet-type adhesive consisting of a conventional liquid epoxy adhesive and an epoxy monolith sheet with internal continuous pores, using the advantageous properties of the flexibility and toughness of the epoxy monolith to avoid stress concentration. We evaluated the adhesion strength for metal bonding using the sheet-type epoxy adhesives via a lap-shear tensile adhesion test at various temperatures. The total destruction energy was also estimated via a tapered double cantilever beam test. Furthermore, a heat cycle adhesion test was conducted using two types of metallic materials with different coefficients of thermal expansion to elucidate the effect of the monolith sheet on the improvement of interfacial failure induced by stress concentration.