The thermal and light induced spin transition in [FeL2](BF4)2 (L = 2,6-dipyrazol-1-yl-4-hydroxymethylpyridine)

This communication presents the crystal structures of the high spin state at 300 K, the low spin state at 30 K and the metastable high spin state after irradiation at 30 K and an estimate of the critical LIESST temperature of [FeL2](BF4)2 which is shown to undergo a spin transition at 271 K.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2004-05 (10), p.1516-1518
Main Authors: Money, V A, Elhaïk, J, Halcrow, M A, Howard, J A K
Format: Article
Language:English
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Summary:This communication presents the crystal structures of the high spin state at 300 K, the low spin state at 30 K and the metastable high spin state after irradiation at 30 K and an estimate of the critical LIESST temperature of [FeL2](BF4)2 which is shown to undergo a spin transition at 271 K.
ISSN:1477-9226
1477-9234
DOI:10.1039/b401155d