Synthesis and reactions of co-ordinatively unsaturated µ 3 -alkylidyne clusters; X-ray crystal structures of the phosphido-bridged complexes [Fe 2 W(µ 3 -CR)(µ-H)(µ-PPh 2 )(CO) 6 (η-C 5 H 5 )], [Fe 2 W(µ 3 -CR)(µ-H)(µ-PEt 2 )(CO) 6 (PEt 2 H)(η-C 5 H 5 )], and [Fe 2 W(µ 3 -CR){µ-C(O)C(Me)CHMe}(µ-PEt 2 )(CO) 5 (η-C 5 H 5 )](R = C 6 H 4 Me-4)

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Published in:Journal of the Chemical Society. Chemical communications 1986 (1), p.17-19
Main Authors: Jeffery, John C., Lawrence-Smith, J. G.
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Language:English
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title Synthesis and reactions of co-ordinatively unsaturated µ 3 -alkylidyne clusters; X-ray crystal structures of the phosphido-bridged complexes [Fe 2 W(µ 3 -CR)(µ-H)(µ-PPh 2 )(CO) 6 (η-C 5 H 5 )], [Fe 2 W(µ 3 -CR)(µ-H)(µ-PEt 2 )(CO) 6 (PEt 2 H)(η-C 5 H 5 )], and [Fe 2 W(µ 3 -CR){µ-C(O)C(Me)CHMe}(µ-PEt 2 )(CO) 5 (η-C 5 H 5 )](R = C 6 H 4 Me-4)
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