A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)] n [Ag(SCN)(CN)] n

The synthesis and structural characterization of a new coordination polymer [Pb(OH)] n [Ag(SCN)(CN)] n , formed by an anionic layer [Ag(CN)(μ3-SCN)] n n− linked to the 1D cationic fragment [Pb(OH)] n through a bridging cyanide, is reported. We have obtained a rational combination of the pattern of l...

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Bibliographic Details
Published in:CrystEngComm 2014-01, Vol.16 (43), p.10040-10045
Main Authors: Diana, Eliano, Gervasio, Giuliana, Priola, Emanuele, Bonometti, Elisabetta
Format: Article
Language:English
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Summary:The synthesis and structural characterization of a new coordination polymer [Pb(OH)] n [Ag(SCN)(CN)] n , formed by an anionic layer [Ag(CN)(μ3-SCN)] n n− linked to the 1D cationic fragment [Pb(OH)] n through a bridging cyanide, is reported. We have obtained a rational combination of the pattern of laurionite-type structures (Pb(OH)X, with X = halogen, SCN) with the 2D hexagonal pattern of the silver thiocyanate. The title compound shows luminescent behaviour, and the analysis of the computed band structure allows us to describe the electronic transitions.
ISSN:1466-8033
1466-8033
DOI:10.1039/C4CE01424C