Terminal conjugated dienes via a ruthenium-catalyzed cross-metathesis/elimination sequence: application to renewable resources

We report a sequence of two ruthenium-catalyzed transformations, namely olefin cross-metathesis with allylic chlorides, followed by elimination, which gives a straightforward access to terminal 1,3-dienes from natural products. Two-step synthesis of terminal 1,3-dienes catalyzed by two different rut...

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Bibliographic Details
Published in:Catalysis science & technology 2014-01, Vol.4 (7), p.264-271
Main Authors: Bilel, Hallouma, Hamdi, Naceur, Zagrouba, Fethi, Fischmeister, Cédric, Bruneau, Christian
Format: Article
Language:English
Subjects:
Catalysis
Chemical Sciences
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Summary:We report a sequence of two ruthenium-catalyzed transformations, namely olefin cross-metathesis with allylic chlorides, followed by elimination, which gives a straightforward access to terminal 1,3-dienes from natural products. Two-step synthesis of terminal 1,3-dienes catalyzed by two different ruthenium complexes.
ISSN:2044-4753
2044-4761
DOI:10.1039/c4cy00315b