Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions

A new polymer supported phosphine free Pd( ii ) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from variou...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances 2014, Vol.4 (50), p.26181-26192
Main Authors: Islam, Sk Manirul, Molla, Rostam Ali, Roy, Anupam Singha, Ghosh, Kajari
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243
cites cdi_FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243
container_end_page 26192
container_issue 50
container_start_page 26181
container_title RSC advances
container_volume 4
creator Islam, Sk Manirul
Molla, Rostam Ali
Roy, Anupam Singha
Ghosh, Kajari
description A new polymer supported phosphine free Pd( ii ) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from various aryl iodides and thiols in the presence of carbon monoxide and polymer supported palladium catalyst. The effects of solvent, base, reaction time and catalyst amount for the thioester synthesis were reported. This catalyst showed excellent catalytic activity and recyclability. The polymer supported Pd( ii ) catalyst could be easily recovered by filtration and reused more than five times without appreciable loss of its initial activity.
doi_str_mv 10.1039/C4RA03338H
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C4RA03338H</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1039_C4RA03338H</sourcerecordid><originalsourceid>FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243</originalsourceid><addsrcrecordid>eNpNkE9Lw0AQxRdRsNRe_AR7FqL7P82xFLWFgkX0HKa7E7KSZsPuVoif3hQFncvMg988Ho-QW87uOZPVw1q9rpiUcrm5IDPBlCkEM9Xlv_uaLFL6YNMYzYXhM5L3oRuPGGk6DUOIGR3dO2ohQzd-TSK3PmDKZ2Dsc4vJJ_rpYSLiIfRjB9mHnoaGQhw72kLnHSZ66t30MbQhDa3vkTYRkdrQO3_G0w25aqBLuPjdc_L-9Pi23hS7l-fterUrrKjKXMASlK4klIxD41BXgNw4dNZwjZpJwQAao5VlTIGRuNRlySyWjRL6wISSc3L342tjSCliUw_RH6ekNWf1ubL6rzL5DTDeYSI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Islam, Sk Manirul ; Molla, Rostam Ali ; Roy, Anupam Singha ; Ghosh, Kajari</creator><creatorcontrib>Islam, Sk Manirul ; Molla, Rostam Ali ; Roy, Anupam Singha ; Ghosh, Kajari</creatorcontrib><description>A new polymer supported phosphine free Pd( ii ) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from various aryl iodides and thiols in the presence of carbon monoxide and polymer supported palladium catalyst. The effects of solvent, base, reaction time and catalyst amount for the thioester synthesis were reported. This catalyst showed excellent catalytic activity and recyclability. The polymer supported Pd( ii ) catalyst could be easily recovered by filtration and reused more than five times without appreciable loss of its initial activity.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA03338H</identifier><language>eng</language><ispartof>RSC advances, 2014, Vol.4 (50), p.26181-26192</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243</citedby><cites>FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>Islam, Sk Manirul</creatorcontrib><creatorcontrib>Molla, Rostam Ali</creatorcontrib><creatorcontrib>Roy, Anupam Singha</creatorcontrib><creatorcontrib>Ghosh, Kajari</creatorcontrib><title>Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions</title><title>RSC advances</title><description>A new polymer supported phosphine free Pd( ii ) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from various aryl iodides and thiols in the presence of carbon monoxide and polymer supported palladium catalyst. The effects of solvent, base, reaction time and catalyst amount for the thioester synthesis were reported. This catalyst showed excellent catalytic activity and recyclability. The polymer supported Pd( ii ) catalyst could be easily recovered by filtration and reused more than five times without appreciable loss of its initial activity.</description><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNkE9Lw0AQxRdRsNRe_AR7FqL7P82xFLWFgkX0HKa7E7KSZsPuVoif3hQFncvMg988Ho-QW87uOZPVw1q9rpiUcrm5IDPBlCkEM9Xlv_uaLFL6YNMYzYXhM5L3oRuPGGk6DUOIGR3dO2ohQzd-TSK3PmDKZ2Dsc4vJJ_rpYSLiIfRjB9mHnoaGQhw72kLnHSZ66t30MbQhDa3vkTYRkdrQO3_G0w25aqBLuPjdc_L-9Pi23hS7l-fterUrrKjKXMASlK4klIxD41BXgNw4dNZwjZpJwQAao5VlTIGRuNRlySyWjRL6wISSc3L342tjSCliUw_RH6ekNWf1ubL6rzL5DTDeYSI</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Islam, Sk Manirul</creator><creator>Molla, Rostam Ali</creator><creator>Roy, Anupam Singha</creator><creator>Ghosh, Kajari</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2014</creationdate><title>Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions</title><author>Islam, Sk Manirul ; Molla, Rostam Ali ; Roy, Anupam Singha ; Ghosh, Kajari</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Islam, Sk Manirul</creatorcontrib><creatorcontrib>Molla, Rostam Ali</creatorcontrib><creatorcontrib>Roy, Anupam Singha</creatorcontrib><creatorcontrib>Ghosh, Kajari</creatorcontrib><collection>CrossRef</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Islam, Sk Manirul</au><au>Molla, Rostam Ali</au><au>Roy, Anupam Singha</au><au>Ghosh, Kajari</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions</atitle><jtitle>RSC advances</jtitle><date>2014</date><risdate>2014</risdate><volume>4</volume><issue>50</issue><spage>26181</spage><epage>26192</epage><pages>26181-26192</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A new polymer supported phosphine free Pd( ii ) complex has been synthesized and characterized. The catalytic performance of the complex has been tested for the carbonylation of aryl halides into aryl thioesters under mild reaction conditions. Thioesters were obtained in excellent yields from various aryl iodides and thiols in the presence of carbon monoxide and polymer supported palladium catalyst. The effects of solvent, base, reaction time and catalyst amount for the thioester synthesis were reported. This catalyst showed excellent catalytic activity and recyclability. The polymer supported Pd( ii ) catalyst could be easily recovered by filtration and reused more than five times without appreciable loss of its initial activity.</abstract><doi>10.1039/C4RA03338H</doi><tpages>12</tpages></addata></record>
fulltext fulltext
identifier ISSN: 2046-2069
ispartof RSC advances, 2014, Vol.4 (50), p.26181-26192
issn 2046-2069
2046-2069
language eng
recordid cdi_crossref_primary_10_1039_C4RA03338H
source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
title Polymer supported Pd catalyzed thioester synthesis via carbonylation of aryl halides under phosphine free conditions
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T03%3A05%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Polymer%20supported%20Pd%20catalyzed%20thioester%20synthesis%20via%20carbonylation%20of%20aryl%20halides%20under%20phosphine%20free%20conditions&rft.jtitle=RSC%20advances&rft.au=Islam,%20Sk%20Manirul&rft.date=2014&rft.volume=4&rft.issue=50&rft.spage=26181&rft.epage=26192&rft.pages=26181-26192&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/C4RA03338H&rft_dat=%3Ccrossref%3E10_1039_C4RA03338H%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c297t-a8a4593a701afde59ae16dedc615e50320aaf654c004a63e85770ce7f425b0243%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true