The palladium( ii ) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki–Miyaura reaction

In this paper we wish to present the first results on the synthesis of N , N -diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium( ii ), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) an...

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Published in:RSC advances 2014, Vol.4 (82), p.43792-43799
Main Authors: Damljanović, Ivan, Stevanović, Dragana, Pejović, Anka, Ilić, Danijela, Živković, Marija, Jovanović, Jovana, Vukićević, Mirjana, Bogdanović, Goran A., Radulović, Niko S., Vukićević, Rastko D.
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cited_by cdi_FETCH-LOGICAL-c231t-6d87c26655575b555733f5cb91dec9a0fa78f9c3eba38d7604c3209268df7a773
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container_end_page 43799
container_issue 82
container_start_page 43792
container_title RSC advances
container_volume 4
creator Damljanović, Ivan
Stevanović, Dragana
Pejović, Anka
Ilić, Danijela
Živković, Marija
Jovanović, Jovana
Vukićević, Mirjana
Bogdanović, Goran A.
Radulović, Niko S.
Vukićević, Rastko D.
description In this paper we wish to present the first results on the synthesis of N , N -diethyl-1-ferrocenyl-3-thiabutanamine, its coordination with palladium( ii ), the complete characterization of the thus obtained complex (including single crystal X-ray analysis for the complex in two polymorphic forms) and screening of its catalytic activity in Suzuki–Miyaura coupling of phenylboronic acid with several aryl bromides. The complex, either purified and then added to the reaction mixture or generated in situ , proved to be an excellent precatalyst in Suzuki–Miyaura coupling. The chemical behavior of the complex in solution was assessed by detailed NMR analyses and cyclic voltammetry measurements which allowed us to draw a number of mechanistic conclusions.
doi_str_mv 10.1039/C4RA08140D
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title The palladium( ii ) complex of N,N-diethyl-1-ferrocenyl-3-thiabutanamine: synthesis, solution and solid state structure and catalytic activity in Suzuki–Miyaura reaction
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