A C 60 -aryne building block: synthesis of a hybrid all-carbon nanostructure

The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the f...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016, Vol.52 (40), p.6677-6680
Main Authors: García, D., Rodríguez-Pérez, L., Herranz, M. A., Peña, D., Guitián, E., Bailey, S., Al-Galiby, Q., Noori, M., Lambert, C. J., Pérez, D., Martín, N.
Format: Article
Language:English
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Summary:The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.
ISSN:1359-7345
1364-548X
DOI:10.1039/C5CC10462A