Efficient electron-promoted desorption of benzene from water ice surfaces

Desorption of benzene (C 6 H 6 ) from solid water surfaces [compact amorphous solid water (c-ASW) and crystalline ice (CI)] during irradiation of ultrathin solid films with low energy (250-300 eV) electrons has been investigated. The observed desorption behaviour is complex but typically two desorpt...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2016, Vol.18 (5), p.426-434
Main Authors: Marchione, Demian, Thrower, John D, McCoustra, Martin R. S
Format: Article
Language:English
Subjects:
Benzene
Clusters
Cross sections
Crystal structure
Desorption
Hydrogen bonding
Islands
Physical chemistry
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Summary:Desorption of benzene (C 6 H 6 ) from solid water surfaces [compact amorphous solid water (c-ASW) and crystalline ice (CI)] during irradiation of ultrathin solid films with low energy (250-300 eV) electrons has been investigated. The observed desorption behaviour is complex but typically two desorption components, with particularly large cross-sections, were present in the observed signal. A fast component, with a cross-section up to 10 −15 cm 2 , is attributed to desorption of isolated C 6 H 6 molecules that are hydrogen-bonded to small clusters of water (H 2 O) molecules on the solid water surface. A slower component, with a cross-section of ca. 10 −17 cm 2 , is attributed mainly to desorption from larger C 6 H 6 islands on the solid water surface. Possible desorption mechanisms are proposed and astrophysical implications are discussed. We study the desorption of benzene from solid water surfaces during irradiation of ultrathin solid films with low energy electrons.
ISSN:1463-9076
1463-9084
DOI:10.1039/c5cp06537b