Synthesis, structural characterization, electronic spectroscopy, and microfluidic detection of Cu +2 and UO 2 +2 [di- tert -butyl-salphenazine] complexes

Metal templation by condensation of 2,3-diaminophenazine with 3,5-di- tert -butyl-2-hydroxybenzaldehyde around the metal centers [M = Cu( ii ), and UO 2 ( vi )] affords a new class of M[di- tert -butyl salphenazine] metal complexes. Reported here is the synthesis, single crystal X-ray structural cha...

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Published in:Dalton transactions : an international journal of inorganic chemistry 2015-02, Vol.44 (10), p.4428-4430
Main Authors: Maynard, B. A., Brooks, J. C., Hardy, E. E., Easley, C. J., Gorden, A. E. V.
Format: Article
Language:English
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Summary:Metal templation by condensation of 2,3-diaminophenazine with 3,5-di- tert -butyl-2-hydroxybenzaldehyde around the metal centers [M = Cu( ii ), and UO 2 ( vi )] affords a new class of M[di- tert -butyl salphenazine] metal complexes. Reported here is the synthesis, single crystal X-ray structural characterization, electronic spectroscopy, and microfluidic detection of the formation of these M[di- tert -butyl sal-phenazine] complexes.
ISSN:1477-9226
1477-9234
DOI:10.1039/C5DT00106D