A high-pressure crystallographic and magnetic study of Na 5 [Mn( l -tart) 2 ]·12H 2 O ( l -tart = l -tartrate)

The crystal structure and magnetic properties of the compound Na 5 [Mn( l -tart) 2 ]·12H 2 O (1, l -tart = l -tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2015, Vol.44 (42), p.18324-18328
Main Authors: Craig, Gavin A., Woodall, Christopher H., McKellar, Scott C., Probert, Michael R., Kamenev, Konstantin V., Moggach, Stephen A., Brechin, Euan K., Parsons, Simon, Murrie, Mark
Format: Article
Language:English
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Summary:The crystal structure and magnetic properties of the compound Na 5 [Mn( l -tart) 2 ]·12H 2 O (1, l -tart = l -tartrate) have been investigated over the pressure range 0.34–3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na + ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.
ISSN:1477-9226
1477-9234
DOI:10.1039/C5DT03320A