A single-stranded {Gd} nanowheel with a symmetric polydentate diacylhydrazone ligand

An unprecedented {Gd 18 } nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, an...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (53), p.8297-83
Main Authors: Wang, Kai, Chen, Zi-Lu, Zou, Hua-Hong, Hu, Kun, Li, Hai-Ye, Zhang, Zhong, Sun, Wei-Yin, Liang, Fu-Pei
Format: Article
Language:English
Subjects:
Lanthanides
Ligands
Nanostructure
Symmetry
Triangles
Wheels
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Summary:An unprecedented {Gd 18 } nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, and shows a large magnetocaloric effect (MCE). A {Gd 18 } nanowheel was solvothermally synthesized. It features a rare single-stranded skeleton that looks like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and the largest size in any pure Ln wheels reported, and shows a large MCE.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc02208a