Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt( ii ), Shimoi-type, η 1 -BH complex

The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η 1 -BH complexes are key intermediates in the process.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016, Vol.52 (54), p.8389-8392
Main Authors: Roselló-Merino, Marta, Rama, Raquel J., Díez, Josefina, Conejero, Salvador
Format: Article
Language:English
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Summary:The platinum complex [Pt(I t Bu′)(I t Bu)][BAr F ] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η 1 -BH complexes are key intermediates in the process.
ISSN:1359-7345
1364-548X
DOI:10.1039/C6CC02720B