Real-time analysis of Pd 2 (dba) 3 activation by phosphine ligands

A combination of UV-Vis spectroscopy and electrospray ionization mass spectrometry is used for real-time monitoring of Pd (dba) activation with sulfonated versions of PPh and Buchwald-type ligands. This provides insight into the effect of ligand and preparation conditions on activation and allows fo...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-01, Vol.53 (5), p.854-856
Main Authors: Janusson, Eric, Zijlstra, Harmen S, Nguyen, Peter P T, MacGillivray, Landon, Martelino, Julio, McIndoe, J Scott
Format: Article
Language:English
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Summary:A combination of UV-Vis spectroscopy and electrospray ionization mass spectrometry is used for real-time monitoring of Pd (dba) activation with sulfonated versions of PPh and Buchwald-type ligands. This provides insight into the effect of ligand and preparation conditions on activation and allows for establishment of rational activation protocols.
ISSN:1359-7345
1364-548X
DOI:10.1039/C6CC08824D