A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity. The oxidative...

Full description

Saved in:
Bibliographic Details
Published in:Organic & biomolecular chemistry 2016-04, Vol.14 (16), p.3883-3888
Main Authors: Loman, Jacob. J, Carnaghan, Emma R, Hamlin, Trevor A, Ovian, John M, Kelly, Christopher B, Mercadante, Michael A, Leadbeater, Nicholas E
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity. The oxidative ring-opening of cyclic ethers using oxoammonium cations is investigated using experimental and computational methods.
ISSN:1477-0520
1477-0539
DOI:10.1039/c6ob00347h