A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations

The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity. The oxidative...

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Published in:Organic & biomolecular chemistry 2016-04, Vol.14 (16), p.3883-3888
Main Authors: Loman, Jacob. J, Carnaghan, Emma R, Hamlin, Trevor A, Ovian, John M, Kelly, Christopher B, Mercadante, Michael A, Leadbeater, Nicholas E
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container_title Organic & biomolecular chemistry
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creator Loman, Jacob. J
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description The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity. The oxidative ring-opening of cyclic ethers using oxoammonium cations is investigated using experimental and computational methods.
doi_str_mv 10.1039/c6ob00347h
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title A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations
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