Carbon dots–quinoline derivative nanocomposite: facile synthesis and application as a “turn-off” fluorescent chemosensor for detection of Cu 2+ ions in tap water

• Published in: RSC advances 2016, Vol.6 (90), p.87230-87236
• Main Authors: Li, Qian, Huang, Qitong, Zhu, Jie-Ji, Ji, Wen-Gang, Tong, Qing-Xiao
• Format: Article
• Language: English
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/C6RA21034A

In this paper, a novel quinoline derivative: 8-(pyridin-2-ylmethoxy)quinoline-2-carboxylic acid (Q) has been successfully synthesized, then it was coupled with carbon dots (CDs) to synthesize a CDs–Q nanocomposite by a simple and green method. The CDs–Q nanocomposite can act as a “turn-off” fluorescent chemosensor for detection of Cu 2+ ions. It's a good candidate for Cu 2+ sensing on account of its excellent properties such as its high sensitivity and selectivity, easy synthesis, excellent fluorescence stability towards temperature and pH, direct detection in aqueous solution and tap water and distinct fluorescence quenching towards Cu 2+ . We have also discussed the fluorescence quenching mechanism of CDs–Q and the possible coordination mode of CDs–Q with Cu 2+ . CDs–Q have a wide linear range (0.01–1.2 μM) and high sensitivity towards Cu 2+ ions with a detection limit of 0.56 nM. In addition, this fluorescent chemosensor was also applied to determine Cu 2+ in tap water with satisfying results.