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Visible-light photocatalytic performances of TiO 2 nanobelts decorated with iron oxide nanocrystals

A TiO 2 –Fe 2 O 3 hetero-nanostructure was fabricated via a three-step method and evaluated for its visible-light photocatalytic performances. TiO 2 nanobelts (NBs) were synthesized by controlled hydrothermal oxidation of a Ti sheet while Fe 2 O 3 nanocrystals (NCs) were prepared by forced hydrolysi...

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Bibliographic Details
Published in:RSC advances 2016, Vol.6 (115), p.114843-114851
Main Authors: Chaguetmi, S., Sobti, N., Decorse, P., Mouton, L., Nowak, S., Mammeri, F., Achour, S., Ammar, S.
Format: Article
Language:English
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Summary:A TiO 2 –Fe 2 O 3 hetero-nanostructure was fabricated via a three-step method and evaluated for its visible-light photocatalytic performances. TiO 2 nanobelts (NBs) were synthesized by controlled hydrothermal oxidation of a Ti sheet while Fe 2 O 3 nanocrystals (NCs) were prepared by forced hydrolysis in polyol. NBs were then decorated with NCs using direct impregnation. The structure, morphology and chemical composition of the resulting hybrids were investigated by X-ray Diffraction (XRD), Field Emission Gun Scanning Electron Microscopy (FEG-SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), Raman and UV-visible diffuse reflectance spectroscopy. The photocatalytic activity was assessed by following methylene blue photodegradation in an aqueous solution under visible light irradiation and comparing to that of bare TiO 2 NBs. The photoelectrochemical properties were determined by measuring their ability to oxidize water under mimetic sunlight irradiation. The significant observed improvement was attributed to sensitization of the wide-gap titania semiconductor by the narrow-gap hematite one, namely faster interfacial charge transfer and wider spectral light absorption.
ISSN:2046-2069
2046-2069
DOI:10.1039/C6RA24415G