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Chemical reduction of CO 2 facilitated by C-nucleophiles
The abundance of atmospheric CO presents both an opportunity and a challenge for synthetic chemists to transform CO into value-added products. A promising strategy involves CO reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This...
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| Published in: | Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (83), p.11390-11398 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c991-1dbf301c43b1009382f399460b500bc29b45a9d32ece9907775cae8f5cfa4dfa3 |
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| cites | cdi_FETCH-LOGICAL-c991-1dbf301c43b1009382f399460b500bc29b45a9d32ece9907775cae8f5cfa4dfa3 |
| container_end_page | 11398 |
| container_issue | 83 |
| container_start_page | 11390 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 53 |
| creator | Janes, Trevor Yang, Yanxin Song, Datong |
| description | The abundance of atmospheric CO
presents both an opportunity and a challenge for synthetic chemists to transform CO
into value-added products. A promising strategy involves CO
reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This approach allows the synthesis of new C-C or C-H bonds from CO
-derived carbon. The first part of this Feature article deals with uncatalyzed reductions of CO
such as insertion into metal-carbon bonds and reactivity towards multidentate actor ligands and metal-free compounds. The second part covers catalytic reduction of CO
in which a nucleophilic C-site is involved. This review brings together two general approaches in the chemical CO
reduction field, showing how the discovery of fundamental reactivity of CO
leads to synthetic applications, and proposes directions for further development. |
| doi_str_mv | 10.1039/c7cc05978g |
| format | article |
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presents both an opportunity and a challenge for synthetic chemists to transform CO
into value-added products. A promising strategy involves CO
reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This approach allows the synthesis of new C-C or C-H bonds from CO
-derived carbon. The first part of this Feature article deals with uncatalyzed reductions of CO
such as insertion into metal-carbon bonds and reactivity towards multidentate actor ligands and metal-free compounds. The second part covers catalytic reduction of CO
in which a nucleophilic C-site is involved. This review brings together two general approaches in the chemical CO
reduction field, showing how the discovery of fundamental reactivity of CO
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presents both an opportunity and a challenge for synthetic chemists to transform CO
into value-added products. A promising strategy involves CO
reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This approach allows the synthesis of new C-C or C-H bonds from CO
-derived carbon. The first part of this Feature article deals with uncatalyzed reductions of CO
such as insertion into metal-carbon bonds and reactivity towards multidentate actor ligands and metal-free compounds. The second part covers catalytic reduction of CO
in which a nucleophilic C-site is involved. This review brings together two general approaches in the chemical CO
reduction field, showing how the discovery of fundamental reactivity of CO
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presents both an opportunity and a challenge for synthetic chemists to transform CO
into value-added products. A promising strategy involves CO
reduction driven by the energy stored in chemical bonds and promoted by molecules containing nucleophilic carbon sites. This approach allows the synthesis of new C-C or C-H bonds from CO
-derived carbon. The first part of this Feature article deals with uncatalyzed reductions of CO
such as insertion into metal-carbon bonds and reactivity towards multidentate actor ligands and metal-free compounds. The second part covers catalytic reduction of CO
in which a nucleophilic C-site is involved. This review brings together two general approaches in the chemical CO
reduction field, showing how the discovery of fundamental reactivity of CO
leads to synthetic applications, and proposes directions for further development.</abstract><cop>England</cop><pmid>28972211</pmid><doi>10.1039/c7cc05978g</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-5469-0495</orcidid><orcidid>https://orcid.org/0000-0001-6622-5980</orcidid></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2017-10, Vol.53 (83), p.11390-11398 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C7CC05978G |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | Chemical reduction of CO 2 facilitated by C-nucleophiles |
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