Enhanced adsorption of small gas molecules in metal (Cu 2+ , Pd 2+ , Pt 2+ ) complexes induced by ligand fluorination

Fully fluorinated coordination complexes, [M(L) 2 ] (M = Cu 2+ , Pd 2+ , Pt 2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1 : 1 selective recognition of CO 2 and metal ion-selective adsorption of small gas molecules such as N 2 , O 2 , H 2 , NO, and CH 4 ,...

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Bibliographic Details
Published in:CrystEngComm 2017, Vol.19 (42), p.6263-6266
Main Authors: Hori, Akiko, Gonda, Ryu, Rzeznicka, Izabela I.
Format: Article
Language:English
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Summary:Fully fluorinated coordination complexes, [M(L) 2 ] (M = Cu 2+ , Pd 2+ , Pt 2+ and L = bis(pentafluorobenzoyl)methanido), show two types of guest recognition events: 1 : 1 selective recognition of CO 2 and metal ion-selective adsorption of small gas molecules such as N 2 , O 2 , H 2 , NO, and CH 4 , while the corresponding non-fluorinated complexes show no guest encapsulation.
ISSN:1466-8033
1466-8033
DOI:10.1039/C7CE01413A