Probing the local structure of Prussian blue electrodes by 113 Cd NMR spectroscopy

We demonstrate that Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li intercalation, providing an atomic-scale insight into the reaction mechanism.

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2017-05, Vol.46 (19), p.6159-6162
Main Authors: Flambard, A, Sugahara, A, De, S, Okubo, M, Yamada, A, Lescouëzec, R
Format: Article
Language:English
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Summary:We demonstrate that Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li intercalation, providing an atomic-scale insight into the reaction mechanism.
ISSN:1477-9226
1477-9234
DOI:10.1039/C7DT00728K