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Water-oxidation photoanodes using organic light-harvesting materials: a review

Solar energy conversion and storage by photoelectrochemical water splitting has garnered significant research attention in recent years. While the majority of water-splitting systems are composed of inorganic semiconductor light-harvesting materials, an increasing amount of research has studied the...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2017, Vol.5 (37), p.19560-19592
Main Authors: Kirner, Joel T., Finke, Richard G.
Format: Article
Language:English
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Summary:Solar energy conversion and storage by photoelectrochemical water splitting has garnered significant research attention in recent years. While the majority of water-splitting systems are composed of inorganic semiconductor light-harvesting materials, an increasing amount of research has studied the use of earth-abundant organic semiconductors and dyes as an inexpensive alternative. Herein, we provide a comprehensive review of published water-oxidizing photoanodes that employ organic light-harvesting materials, including both organic thin-film and dye-sensitized photoelectrochemical cell architectures. We highlight the different materials that have been employed, summarize recent advancements, and provide insights for future improvements of device efficiencies and stabilities.
ISSN:2050-7488
2050-7496
DOI:10.1039/C7TA05709A