Photocatalytic chemoselective cleavage of C-O bonds under hydrogen gas- and acid-free conditions

In the presence of a palladium-loaded TiO 2 photocatalyst, the cleavage of benzyl phenyl ether in low-molecular-weight alcohol solvents under de-aerated conditions afforded toluene and phenol simultaneously in a 1 : 1 molar ratio. In the presence of a palladium-loaded TiO 2 photocatalyst, the cleava...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (53), p.7298-731
Main Authors: Imamura, Kazuya, Kato, Hiroko, Wada, Yuichiro, Makabe, Kazuhiro, Onda, Ayumu, Tanaka, Atsuhiro, Kominami, Hiroshi, Sato, Katsutoshi, Nagaoka, Katsutoshi
Format: Article
Language:English
Subjects:
Aeration
Benzyl phenyl ether
Cleavage
Molecular chains
Palladium
Photocatalysis
Titanium dioxide
Toluene
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Summary:In the presence of a palladium-loaded TiO 2 photocatalyst, the cleavage of benzyl phenyl ether in low-molecular-weight alcohol solvents under de-aerated conditions afforded toluene and phenol simultaneously in a 1 : 1 molar ratio. In the presence of a palladium-loaded TiO 2 photocatalyst, the cleavage of benzyl phenyl ether derivatives afforded toluenes and phenols simultaneously.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc03362e