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Lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen: structures, visible-light-driven photocatalytic properties and enhanced photocurrent responses
The mono-substituted bipyridinium derivative 1-(3-carboxybenzyl)-4,4′-bipyridinium (cbpy) and polyiodide were adopted to construct two new lead-carboxylate hybrids: [Pb(cbpy)I 3 ·I 3 ] n ( 1 ) and {[Pb(cbpy) 2 ](I 3 ) 4 ·I 2 } n ( 2 ), in which interesting halogen bonds were detected. Specifically,...
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| Published in: | CrystEngComm 2018, Vol.2 (16), p.2245-2252 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c318t-86365859e6fa9dfcdea9ae7cda1d5a278d11fbde1ffb2b0f0e1949af548765e73 |
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| cites | cdi_FETCH-LOGICAL-c318t-86365859e6fa9dfcdea9ae7cda1d5a278d11fbde1ffb2b0f0e1949af548765e73 |
| container_end_page | 2252 |
| container_issue | 16 |
| container_start_page | 2245 |
| container_title | CrystEngComm |
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| creator | Zhao, Li-Ming Zhang, Wen-Ting Song, Kai-Yue Wu, Qi-Qi Li, Yi Li, Hao-Hong Chen, Zhi-Rong |
| description | The mono-substituted bipyridinium derivative 1-(3-carboxybenzyl)-4,4′-bipyridinium (cbpy) and polyiodide were adopted to construct two new lead-carboxylate hybrids: [Pb(cbpy)I
3
·I
3
]
n
(
1
) and {[Pb(cbpy)
2
](I
3
)
4
·I
2
}
n
(
2
), in which interesting halogen bonds were detected. Specifically, the hybrids demonstrate efficient photocatalytic degradation of organic dyes and excellent photocurrent response, and the mechanisms of degradation have been discussed and verified using theoretical calculations.
Two lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen have been synthesized, which exhibit efficient photocatalytic degeneration performances. |
| doi_str_mv | 10.1039/c8ce00120k |
| format | article |
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3
·I
3
]
n
(
1
) and {[Pb(cbpy)
2
](I
3
)
4
·I
2
}
n
(
2
), in which interesting halogen bonds were detected. Specifically, the hybrids demonstrate efficient photocatalytic degradation of organic dyes and excellent photocurrent response, and the mechanisms of degradation have been discussed and verified using theoretical calculations.
Two lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen have been synthesized, which exhibit efficient photocatalytic degeneration performances.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c8ce00120k</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Lead ; Photocatalysis ; Photodegradation ; Photoelectric effect ; Photoelectric emission</subject><ispartof>CrystEngComm, 2018, Vol.2 (16), p.2245-2252</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-86365859e6fa9dfcdea9ae7cda1d5a278d11fbde1ffb2b0f0e1949af548765e73</citedby><cites>FETCH-LOGICAL-c318t-86365859e6fa9dfcdea9ae7cda1d5a278d11fbde1ffb2b0f0e1949af548765e73</cites><orcidid>0000-0002-4236-262X ; 0000-0003-3543-7715</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhao, Li-Ming</creatorcontrib><creatorcontrib>Zhang, Wen-Ting</creatorcontrib><creatorcontrib>Song, Kai-Yue</creatorcontrib><creatorcontrib>Wu, Qi-Qi</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Li, Hao-Hong</creatorcontrib><creatorcontrib>Chen, Zhi-Rong</creatorcontrib><title>Lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen: structures, visible-light-driven photocatalytic properties and enhanced photocurrent responses</title><title>CrystEngComm</title><description>The mono-substituted bipyridinium derivative 1-(3-carboxybenzyl)-4,4′-bipyridinium (cbpy) and polyiodide were adopted to construct two new lead-carboxylate hybrids: [Pb(cbpy)I
3
·I
3
]
n
(
1
) and {[Pb(cbpy)
2
](I
3
)
4
·I
2
}
n
(
2
), in which interesting halogen bonds were detected. Specifically, the hybrids demonstrate efficient photocatalytic degradation of organic dyes and excellent photocurrent response, and the mechanisms of degradation have been discussed and verified using theoretical calculations.
Two lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen have been synthesized, which exhibit efficient photocatalytic degeneration performances.</description><subject>Lead</subject><subject>Photocatalysis</subject><subject>Photodegradation</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNkUFP3DAQhaOqSKW0l94rWeJWEbCTTdbpDa2goK7EhZ6jiT3emGbtMHYQ-W_8uLqbinKa0cw37430suyL4OeCl82Fkgo5FwX__S47Fqu6ziUvy_dv-g_ZxxAeErMSgh9nL1sEnSugzj_PA0S8GP0wW6-tRtbPHVkdmPIuRJpURM0M-T3rYfA7dKzzTlu3Y-A0gzDv9xjJKvZk_WH_nS1nE2E4S9NguwHzwe76mGuyT0lh7H30CiIMc0yXI_kRKVoMB010PTiVXBdsIkIXWVIb00cYPmVHBoaAn__Vk-zX9dX95ibf3v243Vxuc1UKGXNZl3UlqwZrA402SiM0gGulQegKirXUQphOozCmKzpuOIpm1YCpVnJdV7guT7LTRTe99zhhiO2Dn8gly7bgRVNLUQmRqG8LpciHQGjakeweaG4Fb_-m027k5uqQzs8Ef11gCuqV-59e-QeJAJQf</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Zhao, Li-Ming</creator><creator>Zhang, Wen-Ting</creator><creator>Song, Kai-Yue</creator><creator>Wu, Qi-Qi</creator><creator>Li, Yi</creator><creator>Li, Hao-Hong</creator><creator>Chen, Zhi-Rong</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-4236-262X</orcidid><orcidid>https://orcid.org/0000-0003-3543-7715</orcidid></search><sort><creationdate>2018</creationdate><title>Lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen: structures, visible-light-driven photocatalytic properties and enhanced photocurrent responses</title><author>Zhao, Li-Ming ; Zhang, Wen-Ting ; Song, Kai-Yue ; Wu, Qi-Qi ; Li, Yi ; Li, Hao-Hong ; Chen, Zhi-Rong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-86365859e6fa9dfcdea9ae7cda1d5a278d11fbde1ffb2b0f0e1949af548765e73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Lead</topic><topic>Photocatalysis</topic><topic>Photodegradation</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Li-Ming</creatorcontrib><creatorcontrib>Zhang, Wen-Ting</creatorcontrib><creatorcontrib>Song, Kai-Yue</creatorcontrib><creatorcontrib>Wu, Qi-Qi</creatorcontrib><creatorcontrib>Li, Yi</creatorcontrib><creatorcontrib>Li, Hao-Hong</creatorcontrib><creatorcontrib>Chen, Zhi-Rong</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Li-Ming</au><au>Zhang, Wen-Ting</au><au>Song, Kai-Yue</au><au>Wu, Qi-Qi</au><au>Li, Yi</au><au>Li, Hao-Hong</au><au>Chen, Zhi-Rong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen: structures, visible-light-driven photocatalytic properties and enhanced photocurrent responses</atitle><jtitle>CrystEngComm</jtitle><date>2018</date><risdate>2018</risdate><volume>2</volume><issue>16</issue><spage>2245</spage><epage>2252</epage><pages>2245-2252</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>The mono-substituted bipyridinium derivative 1-(3-carboxybenzyl)-4,4′-bipyridinium (cbpy) and polyiodide were adopted to construct two new lead-carboxylate hybrids: [Pb(cbpy)I
3
·I
3
]
n
(
1
) and {[Pb(cbpy)
2
](I
3
)
4
·I
2
}
n
(
2
), in which interesting halogen bonds were detected. Specifically, the hybrids demonstrate efficient photocatalytic degradation of organic dyes and excellent photocurrent response, and the mechanisms of degradation have been discussed and verified using theoretical calculations.
Two lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen have been synthesized, which exhibit efficient photocatalytic degeneration performances.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8ce00120k</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-4236-262X</orcidid><orcidid>https://orcid.org/0000-0003-3543-7715</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018, Vol.2 (16), p.2245-2252 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8CE00120K |
| source | Royal Society of Chemistry |
| subjects | Lead Photocatalysis Photodegradation Photoelectric effect Photoelectric emission |
| title | Lead-carboxylate/polyiodide hybrids constructed from halogen bonding and asymmetric viologen: structures, visible-light-driven photocatalytic properties and enhanced photocurrent responses |
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