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Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching
Five transition metal-BTC-BIm based coordination polymers, namely [Zn 2 (HBTC) 2 (BIm) 2 (H 2 O) 2 ]·(H 2 O) 3 , 1 ; [2-HABI] 2 [Zn 2 (BTC) 2 (2-ABI)(H 2 O)]·(H 2 O) 5 , 2 ; [Cu 3 (BTC) 2 (BIm) 6 ][solvent], 3 ; [Co 4 (BTC) 3 (BIm) 6 ][solvent], 4 ; and [(CH 3 CH 2 ) 2 NH 2 ][Zn(BTC)(BIm)]·(H 2 O),...
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| Published in: | CrystEngComm 2018, Vol.2 (41), p.662-6612 |
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| Language: | English |
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| creator | Tiwari, Ranjay K Behera, J. N |
| description | Five transition metal-BTC-BIm based coordination polymers, namely [Zn
2
(HBTC)
2
(BIm)
2
(H
2
O)
2
]·(H
2
O)
3
,
1
; [2-HABI]
2
[Zn
2
(BTC)
2
(2-ABI)(H
2
O)]·(H
2
O)
5
,
2
; [Cu
3
(BTC)
2
(BIm)
6
][solvent],
3
; [Co
4
(BTC)
3
(BIm)
6
][solvent],
4
; and [(CH
3
CH
2
)
2
NH
2
][Zn(BTC)(BIm)]·(H
2
O),
5
have been synthesized and characterized using complementary techniques like single crystal X-ray analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA) (BTC = 1,3,5-benzene tricarboxylic acid, BIm = benzimidazole and 2-ABI = 2-aminobenzimidazole). Crystal structure analysis of these compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers while
4
and
5
have three-dimensional architectures.
3
forms a hexagonal bronze sheet,
4
has a three-dimensional network with embedded paddlewheel SBUs and helical assembly, and
5
crystallizes in a polar space group (
Pna
2
1
) with 3D helical networks with adamantane-type topology. The dielectric properties of
5
showed that the dielectric constant rapidly decreases with an increase in frequency suggesting dipole relaxation at low frequencies.
Five transition metal-BTC-BIm based coordination polymers with hierarchical structures were synthesized under hydro/solvothermal condition. Crystal structure analysis of the compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers, while
4
and
5
have three-dimensional architectures. |
| doi_str_mv | 10.1039/c8ce01299g |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1039_C8CE01299G</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2124122030</sourcerecordid><originalsourceid>FETCH-LOGICAL-c318t-776ea0fe1c79726c97ee999c2c601cd689c6521819aac843034328d56dadedda3</originalsourceid><addsrcrecordid>eNpNkEtLAzEUhYMoWKsb90LAnTCaxzQzcadDtULBTV0PtzdpmzKPmmTU9tc7WlFX9yy-cw98hJxzds2Z1DeYo2VcaL08IAOeKpXkTMrDf_mYnISwZoynnLMB-Zhs594ZWkO03kEV6ByCNbRtaPTQBBddH2sboUruZ0Uyt83O1c7Arq3sLQ1t9WabSCEEF2LfQ78NPVu1Sw-blUMKjaEh-g5j56Gi4d1FXLlmeUqOFv2cPfu5Q_LyMJ4Vk2T6_PhU3E0TlDyPSZYpC2xhOWY6Ewp1Zq3WGgUqxtGoXKMaCZ5zDYB5KplMpcjNSBkw1hiQQ3K5_7vx7WtnQyzXbeebfrIUXKRcCNaXhuRqT6FvQ_B2UW68q8FvS87KL7NlkRfjb7OPPXyxh33AX-7PvPwEe5V4AA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2124122030</pqid></control><display><type>article</type><title>Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching</title><source>Royal Society of Chemistry</source><creator>Tiwari, Ranjay K ; Behera, J. N</creator><creatorcontrib>Tiwari, Ranjay K ; Behera, J. N</creatorcontrib><description>Five transition metal-BTC-BIm based coordination polymers, namely [Zn
2
(HBTC)
2
(BIm)
2
(H
2
O)
2
]·(H
2
O)
3
,
1
; [2-HABI]
2
[Zn
2
(BTC)
2
(2-ABI)(H
2
O)]·(H
2
O)
5
,
2
; [Cu
3
(BTC)
2
(BIm)
6
][solvent],
3
; [Co
4
(BTC)
3
(BIm)
6
][solvent],
4
; and [(CH
3
CH
2
)
2
NH
2
][Zn(BTC)(BIm)]·(H
2
O),
5
have been synthesized and characterized using complementary techniques like single crystal X-ray analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA) (BTC = 1,3,5-benzene tricarboxylic acid, BIm = benzimidazole and 2-ABI = 2-aminobenzimidazole). Crystal structure analysis of these compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers while
4
and
5
have three-dimensional architectures.
3
forms a hexagonal bronze sheet,
4
has a three-dimensional network with embedded paddlewheel SBUs and helical assembly, and
5
crystallizes in a polar space group (
Pna
2
1
) with 3D helical networks with adamantane-type topology. The dielectric properties of
5
showed that the dielectric constant rapidly decreases with an increase in frequency suggesting dipole relaxation at low frequencies.
Five transition metal-BTC-BIm based coordination polymers with hierarchical structures were synthesized under hydro/solvothermal condition. Crystal structure analysis of the compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers, while
4
and
5
have three-dimensional architectures.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/c8ce01299g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aminobenzimidazole ; Coordination polymers ; Crystal structure ; Crystallography ; Dielectric properties ; Dielectric relaxation ; Diffraction ; Single crystals ; Solvents ; Structural analysis ; Switching theory ; Thermogravimetric analysis ; Transition metals ; Trimesic acid ; X ray analysis ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>CrystEngComm, 2018, Vol.2 (41), p.662-6612</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c318t-776ea0fe1c79726c97ee999c2c601cd689c6521819aac843034328d56dadedda3</citedby><cites>FETCH-LOGICAL-c318t-776ea0fe1c79726c97ee999c2c601cd689c6521819aac843034328d56dadedda3</cites><orcidid>0000-0003-1161-588X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Tiwari, Ranjay K</creatorcontrib><creatorcontrib>Behera, J. N</creatorcontrib><title>Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching</title><title>CrystEngComm</title><description>Five transition metal-BTC-BIm based coordination polymers, namely [Zn
2
(HBTC)
2
(BIm)
2
(H
2
O)
2
]·(H
2
O)
3
,
1
; [2-HABI]
2
[Zn
2
(BTC)
2
(2-ABI)(H
2
O)]·(H
2
O)
5
,
2
; [Cu
3
(BTC)
2
(BIm)
6
][solvent],
3
; [Co
4
(BTC)
3
(BIm)
6
][solvent],
4
; and [(CH
3
CH
2
)
2
NH
2
][Zn(BTC)(BIm)]·(H
2
O),
5
have been synthesized and characterized using complementary techniques like single crystal X-ray analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA) (BTC = 1,3,5-benzene tricarboxylic acid, BIm = benzimidazole and 2-ABI = 2-aminobenzimidazole). Crystal structure analysis of these compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers while
4
and
5
have three-dimensional architectures.
3
forms a hexagonal bronze sheet,
4
has a three-dimensional network with embedded paddlewheel SBUs and helical assembly, and
5
crystallizes in a polar space group (
Pna
2
1
) with 3D helical networks with adamantane-type topology. The dielectric properties of
5
showed that the dielectric constant rapidly decreases with an increase in frequency suggesting dipole relaxation at low frequencies.
Five transition metal-BTC-BIm based coordination polymers with hierarchical structures were synthesized under hydro/solvothermal condition. Crystal structure analysis of the compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers, while
4
and
5
have three-dimensional architectures.</description><subject>Aminobenzimidazole</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Dielectric properties</subject><subject>Dielectric relaxation</subject><subject>Diffraction</subject><subject>Single crystals</subject><subject>Solvents</subject><subject>Structural analysis</subject><subject>Switching theory</subject><subject>Thermogravimetric analysis</subject><subject>Transition metals</subject><subject>Trimesic acid</subject><subject>X ray analysis</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpNkEtLAzEUhYMoWKsb90LAnTCaxzQzcadDtULBTV0PtzdpmzKPmmTU9tc7WlFX9yy-cw98hJxzds2Z1DeYo2VcaL08IAOeKpXkTMrDf_mYnISwZoynnLMB-Zhs594ZWkO03kEV6ByCNbRtaPTQBBddH2sboUruZ0Uyt83O1c7Arq3sLQ1t9WabSCEEF2LfQ78NPVu1Sw-blUMKjaEh-g5j56Gi4d1FXLlmeUqOFv2cPfu5Q_LyMJ4Vk2T6_PhU3E0TlDyPSZYpC2xhOWY6Ewp1Zq3WGgUqxtGoXKMaCZ5zDYB5KplMpcjNSBkw1hiQQ3K5_7vx7WtnQyzXbeebfrIUXKRcCNaXhuRqT6FvQ_B2UW68q8FvS87KL7NlkRfjb7OPPXyxh33AX-7PvPwEe5V4AA</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Tiwari, Ranjay K</creator><creator>Behera, J. N</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-1161-588X</orcidid></search><sort><creationdate>2018</creationdate><title>Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching</title><author>Tiwari, Ranjay K ; Behera, J. N</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c318t-776ea0fe1c79726c97ee999c2c601cd689c6521819aac843034328d56dadedda3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aminobenzimidazole</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Dielectric properties</topic><topic>Dielectric relaxation</topic><topic>Diffraction</topic><topic>Single crystals</topic><topic>Solvents</topic><topic>Structural analysis</topic><topic>Switching theory</topic><topic>Thermogravimetric analysis</topic><topic>Transition metals</topic><topic>Trimesic acid</topic><topic>X ray analysis</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tiwari, Ranjay K</creatorcontrib><creatorcontrib>Behera, J. N</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tiwari, Ranjay K</au><au>Behera, J. N</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching</atitle><jtitle>CrystEngComm</jtitle><date>2018</date><risdate>2018</risdate><volume>2</volume><issue>41</issue><spage>662</spage><epage>6612</epage><pages>662-6612</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Five transition metal-BTC-BIm based coordination polymers, namely [Zn
2
(HBTC)
2
(BIm)
2
(H
2
O)
2
]·(H
2
O)
3
,
1
; [2-HABI]
2
[Zn
2
(BTC)
2
(2-ABI)(H
2
O)]·(H
2
O)
5
,
2
; [Cu
3
(BTC)
2
(BIm)
6
][solvent],
3
; [Co
4
(BTC)
3
(BIm)
6
][solvent],
4
; and [(CH
3
CH
2
)
2
NH
2
][Zn(BTC)(BIm)]·(H
2
O),
5
have been synthesized and characterized using complementary techniques like single crystal X-ray analysis, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA) (BTC = 1,3,5-benzene tricarboxylic acid, BIm = benzimidazole and 2-ABI = 2-aminobenzimidazole). Crystal structure analysis of these compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers while
4
and
5
have three-dimensional architectures.
3
forms a hexagonal bronze sheet,
4
has a three-dimensional network with embedded paddlewheel SBUs and helical assembly, and
5
crystallizes in a polar space group (
Pna
2
1
) with 3D helical networks with adamantane-type topology. The dielectric properties of
5
showed that the dielectric constant rapidly decreases with an increase in frequency suggesting dipole relaxation at low frequencies.
Five transition metal-BTC-BIm based coordination polymers with hierarchical structures were synthesized under hydro/solvothermal condition. Crystal structure analysis of the compounds showed that
1
forms a 1D chain,
2
and
3
have 2D layers, while
4
and
5
have three-dimensional architectures.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c8ce01299g</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-1161-588X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2018, Vol.2 (41), p.662-6612 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8CE01299G |
| source | Royal Society of Chemistry |
| subjects | Aminobenzimidazole Coordination polymers Crystal structure Crystallography Dielectric properties Dielectric relaxation Diffraction Single crystals Solvents Structural analysis Switching theory Thermogravimetric analysis Transition metals Trimesic acid X ray analysis X ray powder diffraction X-ray diffraction |
| title | Hybrid materials based on transition metal-BTC-benzimidazole: solvent assisted crystallographic and structural switching |
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