Fabrication of a novel few-layer WS 2 /Bi 2 MoO 6 plate-on-plate heterojunction structure with enhanced visible-light photocatalytic activity

• Published in: Dalton transactions : an international journal of inorganic chemistry 2018-07, Vol.47 (30), p.10046-10056
• Main Authors: Li, Xiang, Su, Mengyuan, Zhu, Guifen, Zhang, Kaige, Zhang, Xia, Fan, Jing
• Format: Article
• Language: English
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/C8DT02109K

In this study, a novel few-layer WS2/Bi2MoO6 heterojunction with greatly enhanced visible light photocatalytic performance was synthesized via a facile hydrothermal method. The results indicated that Bi2MoO6 nanosheets were directly grown on the surface of few-layer WS2 and form plate-on-plate heterojunctions. The synthesized nanocomposites exhibited excellent photocatalytic activity under visible-light irradiation. The optimal composite with 5 wt% WS2 showed the highest photocatalytic activity, whose degradation efficiencies and TOC removal were 99.5% and 91.7% for rhodamine B (RhB), 98.9% and 89.8% for ciprofloxacin (CIP), 76.0% and 67.8% for methylene blue (MB), and 69.3% and 58.6% for methimazole (MMI), respectively. Their excellent photocatalytic performance was predominantly ascribed to the construction of a plate-on-plate heterojunction structure between WS2 and Bi2MoO6, which could promote charge separation efficiency and enhance light harvesting efficiency. The present work provides a new understanding for extending the application of transition-metal dichalcogenides in the field of photocatalysis.