Platinum-mediated monohydration of SO 2

The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavore...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018-12, Vol.47 (47), p.16846-16849
Main Authors: Gimeno-Prat, Antonio, Cortés-Sanchón, Adrián, Martín, Antonio, Baya, Miguel, Casas, José M
Format: Article
Language:English
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Summary:The monohydration of SO2 has been achieved in solution mediated by a platinum-aquo complex. Benzamidate ligands play a key role along the process, acting as versatile proton shuttles. Finally, the platinum center allows the stabilization of benzimidic acid and a hydrogensulphite anion, the disfavored tautomers of benzamide and sulphonate, respectively.
ISSN:1477-9226
1477-9234
DOI:10.1039/C8DT04169E