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Use of γ-valerolactone and glycerol derivatives as bio-based renewable solvents for membrane preparation
Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources. It would be beneficial to replace common solvents, like N , N -dimethylacetamide (DMA), N , N -dimethylformamide (DMF) and tetrahydrofuran, by "green" solv...
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| Published in: | Green chemistry : an international journal and green chemistry resource : GC 2019-03, Vol.21 (5), p.154-164 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c196t-c26c5ffabccb1fb596a07b18bc84f62386e61285d6dd7ca4231d2e323962317b3 |
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| cites | cdi_FETCH-LOGICAL-c196t-c26c5ffabccb1fb596a07b18bc84f62386e61285d6dd7ca4231d2e323962317b3 |
| container_end_page | 164 |
| container_issue | 5 |
| container_start_page | 154 |
| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 21 |
| creator | Rasool, M. A Vankelecom, I. F. J |
| description | Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources. It would be beneficial to replace common solvents, like
N
,
N
-dimethylacetamide (DMA),
N
,
N
-dimethylformamide (DMF) and tetrahydrofuran, by "green" solvents. Among these, bio-based solvents were selected for this research, more specifically γ-valerolactone (GVL) and a set of glycerol derivatives. They were screened for their potential use as solvent for membrane preparation by determining solubility of a variety of common membrane polymers and by verifying their applicability in the process of phase inversion to create useful membranes with appropriate pore structures and separation properties. Polymer solubility was rationalized by Hansen solubility parameters. Membrane morphology was characterized by using scanning electron microscopy, while membrane performance was investigated using rose bengal (1017 Da) in water as feed to screen the potential to tune these polymer/solvent systems even toward the nanofiltration range.
Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources. |
| doi_str_mv | 10.1039/c8gc03652g |
| format | article |
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N
,
N
-dimethylacetamide (DMA),
N
,
N
-dimethylformamide (DMF) and tetrahydrofuran, by "green" solvents. Among these, bio-based solvents were selected for this research, more specifically γ-valerolactone (GVL) and a set of glycerol derivatives. They were screened for their potential use as solvent for membrane preparation by determining solubility of a variety of common membrane polymers and by verifying their applicability in the process of phase inversion to create useful membranes with appropriate pore structures and separation properties. Polymer solubility was rationalized by Hansen solubility parameters. Membrane morphology was characterized by using scanning electron microscopy, while membrane performance was investigated using rose bengal (1017 Da) in water as feed to screen the potential to tune these polymer/solvent systems even toward the nanofiltration range.
Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/c8gc03652g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Derivatives ; Dimethylformamide ; Glycerol ; Green chemistry ; Membranes ; Morphology ; Nanofiltration ; Nanotechnology ; Polymer solubility ; Polymers ; Scanning electron microscopy ; Solubility ; Solubility parameters ; Solvents ; Tetrahydrofuran</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2019-03, Vol.21 (5), p.154-164</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c196t-c26c5ffabccb1fb596a07b18bc84f62386e61285d6dd7ca4231d2e323962317b3</citedby><cites>FETCH-LOGICAL-c196t-c26c5ffabccb1fb596a07b18bc84f62386e61285d6dd7ca4231d2e323962317b3</cites><orcidid>0000-0002-6504-2311 ; 0000-0002-0104-9493</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Rasool, M. A</creatorcontrib><creatorcontrib>Vankelecom, I. F. J</creatorcontrib><title>Use of γ-valerolactone and glycerol derivatives as bio-based renewable solvents for membrane preparation</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources. It would be beneficial to replace common solvents, like
N
,
N
-dimethylacetamide (DMA),
N
,
N
-dimethylformamide (DMF) and tetrahydrofuran, by "green" solvents. Among these, bio-based solvents were selected for this research, more specifically γ-valerolactone (GVL) and a set of glycerol derivatives. They were screened for their potential use as solvent for membrane preparation by determining solubility of a variety of common membrane polymers and by verifying their applicability in the process of phase inversion to create useful membranes with appropriate pore structures and separation properties. Polymer solubility was rationalized by Hansen solubility parameters. Membrane morphology was characterized by using scanning electron microscopy, while membrane performance was investigated using rose bengal (1017 Da) in water as feed to screen the potential to tune these polymer/solvent systems even toward the nanofiltration range.
Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources.</description><subject>Derivatives</subject><subject>Dimethylformamide</subject><subject>Glycerol</subject><subject>Green chemistry</subject><subject>Membranes</subject><subject>Morphology</subject><subject>Nanofiltration</subject><subject>Nanotechnology</subject><subject>Polymer solubility</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Solubility</subject><subject>Solubility parameters</subject><subject>Solvents</subject><subject>Tetrahydrofuran</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkM9KxDAQh4MouK5evAsBb0I1f5qkPUrRVVjw4p5Lkk5Kl25Tk25ln8v38JnsurKeZpj55jfwIXRNyT0lPH-wWW0Jl4LVJ2hGU8mTnClyeuwlO0cXMa4JoVTJdIaaVQTsHf7-SkbdQvCttoPvAOuuwnW7s_sRriA0ox6aESLWEZvGJ0ZHqHCADj61aQFH347QDRE7H_AGNiboKaUP0OswXfruEp053Ua4-qtztHp-ei9ekuXb4rV4XCaW5nJILJNWOKeNtYY6I3KpiTI0MzZLnWQ8kyApy0Qlq0pZnTJOKwac8XxaUmX4HN0ecvvgP7YQh3Ltt6GbXpaMZkrkQigxUXcHygYfYwBX9qHZ6LArKSn3KssiWxS_KhcTfHOAQ7RH7l81_wHjxnKO</recordid><startdate>20190304</startdate><enddate>20190304</enddate><creator>Rasool, M. A</creator><creator>Vankelecom, I. F. J</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-6504-2311</orcidid><orcidid>https://orcid.org/0000-0002-0104-9493</orcidid></search><sort><creationdate>20190304</creationdate><title>Use of γ-valerolactone and glycerol derivatives as bio-based renewable solvents for membrane preparation</title><author>Rasool, M. A ; Vankelecom, I. F. J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c196t-c26c5ffabccb1fb596a07b18bc84f62386e61285d6dd7ca4231d2e323962317b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Derivatives</topic><topic>Dimethylformamide</topic><topic>Glycerol</topic><topic>Green chemistry</topic><topic>Membranes</topic><topic>Morphology</topic><topic>Nanofiltration</topic><topic>Nanotechnology</topic><topic>Polymer solubility</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Solubility</topic><topic>Solubility parameters</topic><topic>Solvents</topic><topic>Tetrahydrofuran</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rasool, M. A</creatorcontrib><creatorcontrib>Vankelecom, I. F. J</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rasool, M. A</au><au>Vankelecom, I. F. J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Use of γ-valerolactone and glycerol derivatives as bio-based renewable solvents for membrane preparation</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2019-03-04</date><risdate>2019</risdate><volume>21</volume><issue>5</issue><spage>154</spage><epage>164</epage><pages>154-164</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Current solvents used in membrane preparation are often toxic, environmentally unfriendly and prepared from non-sustainable resources. It would be beneficial to replace common solvents, like
N
,
N
-dimethylacetamide (DMA),
N
,
N
-dimethylformamide (DMF) and tetrahydrofuran, by "green" solvents. Among these, bio-based solvents were selected for this research, more specifically γ-valerolactone (GVL) and a set of glycerol derivatives. They were screened for their potential use as solvent for membrane preparation by determining solubility of a variety of common membrane polymers and by verifying their applicability in the process of phase inversion to create useful membranes with appropriate pore structures and separation properties. Polymer solubility was rationalized by Hansen solubility parameters. Membrane morphology was characterized by using scanning electron microscopy, while membrane performance was investigated using rose bengal (1017 Da) in water as feed to screen the potential to tune these polymer/solvent systems even toward the nanofiltration range.
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| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2019-03, Vol.21 (5), p.154-164 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C8GC03652G |
| source | Royal Society of Chemistry |
| subjects | Derivatives Dimethylformamide Glycerol Green chemistry Membranes Morphology Nanofiltration Nanotechnology Polymer solubility Polymers Scanning electron microscopy Solubility Solubility parameters Solvents Tetrahydrofuran |
| title | Use of γ-valerolactone and glycerol derivatives as bio-based renewable solvents for membrane preparation |
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