Luminescent enhancement study of 3Tb,5Ce,5Li:CaF 2 : effect of Li + ion concentration and hyperthermia applications of 3Tb:CaF 2 /Fe 3 O 4 nanocomposite

• Published in: New journal of chemistry 2019-01, Vol.43 (3), p.1328-1339
• Main Authors: Singh, Ningthoujam Premananda, Kumam, Nandini, Singh, Laishram Priyobarta, Singh, Nongmaithem Rajmuhon, Srivastava, Sri Krishna
• Format: Article
• Language: English
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/C8NJ04057E

CaF 2 nanomaterials doped with Tb 3+ ions (3Tb:CaF 2 ) were synthesized using ethylene glycol as a capping agent. Further, a requisite amount of Ce 3+ ions and Li + ions were codoped into 3Tb:CaF 2 to produce 3Tb,5Ce,5Li:CaF 2 with the optimal concentrations of 5 at% each for the Ce 3+ and Li + ions. Lanthanide and alkaline ions were successfully incorporated into the host lattice, and the tensile strain produced during their incorporation into the host CaF 2 nanoparticles was also calculated. A good luminescence improvement was observed in the nanoparticles containing the Ce 3+ and Tb 3+ ion-codoped CaF 2 due to the strong energy transfer from the Ce 3+ ions to Tb 3+ ions. The luminescence intensity of these green light-emitting nanomaterials was further intensified 2.2 fold after the addition of Li + ions as a codopant. The enhancement in luminescence intensity with Li + ion codoping is related to the decrease in both non-radiative rate and tensile strain. The 3Tb:CaF 2 /Fe 3 O 4 nanocomposite showed heating ability up to 42 °C (hyperthermia temperature) under an AC magnetic field within a short time. Furthermore, this nanocomposite showed high biocompatibility with HeLa cancer cells.