Surface conversion of ZnO nanorods to ZIF-8 to suppress surface defects for a visible-blind UV photodetector

• Published in: Nanoscale 2018-12, Vol.1 (45), p.21168-21177
• Main Authors: Kim, Hyeonghun, Kim, Woochul, Park, Jiyoon, Lim, Namsoo, Lee, Ryeri, Cho, Sung Jun, Kumaresan, Yogeenth, Oh, Myoung-Kyu, Jung, Gun Young
• Format: Article
• Language: English
• Subjects: Defects; Gold; Light; Metal-organic frameworks; Nanomaterials; Nanorods; Photometers; Reflectance; Surface defects; Ultraviolet radiation; Zinc oxide
• ISSN: 2040-3364; 2040-3372
• DOI: 10.1039/c8nr06701e

ZnO nanomaterials are promising building blocks for an efficient UV photodetector; however, their slow sensing behavior and undesired response to visible light, which are attributed to surface defects, such as oxygen or zinc vacancies, are challenges that remain to be addressed. Here, we transformed the ZnO nanorod surface into a zeolitic imidazolate framework-8 (ZIF-8) to eliminate ZnO surface defects. Vertical-type photodetectors were fabricated incorporating a Schottky junction at the ZIF-8/gold (Au) top electrode and could respond to UV light with a rapid response and recovery (1-2 s) and demonstrated a UV-to-visible rejection ratio in the order of 10 3 , qualifying them as efficient visible-blind UV photodetectors. It is noteworthy that the ZIF-8 layer effectively separated the photogenerated electron-hole pairs, and thus reduced their recombination probability. The enhanced photodetector displayed excellent figures-of-merit: a responsivity of 291 A W −1 and a detectivity of 5.9 × 10 13 cm Hz 1/2 W −1 under illumination at 295 nm. A remarkably sensitive and visible-blind ultraviolet photodetector based on ZnO nanorods is demonstrated through ZnO surface conversion into ZIF-8.