Thin film properties and stability of a potential molecular quantum bit based on copper()

• Published in: Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2018, Vol.6 (3), p.828-834
• Main Authors: Ciccullo, Francesca, Glaser, Mathias, Sättele, Marie S, Lenz, Samuel, Neugebauer, Petr, Rechkemmer, Yvonne, van Slageren, Joris, Casu, M. Benedetta
• Format: Article
• Language: English
• Subjects: Control stability; Coordination compounds; Copper; Copper compounds; Dichroism; Electron paramagnetic resonance; Qubits (quantum computing); Spectroscopy; Spectrum analysis; Thin films
• ISSN: 2050-7526; 2050-7534
• DOI: 10.1039/c8tc02610f

We have investigated the thin films of a copper( ii ) β-diketonate complex by using a multi-technique approach including X-ray photoelectron spectroscopy, high-frequency electron paramagnetic resonance, and magnetic circular dichroism spectroscopy. This complex, Cu(dbm) 2 (Hdbm is dibenzoyl methane), is a potential molecular quantum bit. We have demonstrated that Cu(dbm) 2 can be successfully evaporated under controlled conditions. We have further studied the stability of the obtained films in air down to the monolayer regime. The results show that Cu(dbm) 2 thin films have very good stability, also in comparison to other potential molecular quantum bits. Understanding the stability of this class of materials plays an important role when moving from academic investigations to environments that mimic those of working devices. In this respect, thermally and air stable thin films are a key step towards applications. Cu(dbm) 2 , a molecular quantum bit, forms very thermally and air-stable films. This is a key step towards applications.