A robust photocatalyst of Au 25 @ZIF-8@TiO 2 -ReP with dual photoreductive sites to promote photoelectron utilization in H 2 O splitting to H 2 and CO 2 reduction to CO

Sustaining long-term chemical or photochemical stability of a homogeneous molecular catalyst remains a significant challenge. We report a remarkable improvement of the activity and stability of a Au 25 @ZIF-8@TiO 2 -ReP catalyst via composition engineering with double redox active sites of Au 25 NCs...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2019-10, Vol.55 (86), p.12976-12979
Main Authors: Tian, Linyuan, Luo, Yucheng, Chu, Kunlin, Wu, Dongjun, Shi, Jianying, Liang, Zhenxing
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Sustaining long-term chemical or photochemical stability of a homogeneous molecular catalyst remains a significant challenge. We report a remarkable improvement of the activity and stability of a Au 25 @ZIF-8@TiO 2 -ReP catalyst via composition engineering with double redox active sites of Au 25 NCs and a Re( i ) complex for H 2 and CO evolution to promote electron utilization.
ISSN:1359-7345
1364-548X
DOI:10.1039/C9CC07014A