π-Conjugated polymeric phthalocyanine for the oxidative coupling of amines

A cross-linked π-conjugated polymeric cobalt phthalocyanine material was developed by a facile, economical, scalable, and solid-phase synthesis method. In addition to being highly recyclable, this material showed greatly enhanced activity for the aerobic oxidative coupling of amines compared with a...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2020-03, Vol.56 (25), p.3637-364
Main Authors: Wu, Haihong, Cao, Yanwei, Zhu, Gangli, Zeng, Dehong, Zhu, Xiang, Du, Jimin, He, Lin
Format: Article
Language:English
Subjects:
Amines
Coupling (molecular)
Crosslinking
Solid phase synthesis
Solid phases
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Summary:A cross-linked π-conjugated polymeric cobalt phthalocyanine material was developed by a facile, economical, scalable, and solid-phase synthesis method. In addition to being highly recyclable, this material showed greatly enhanced activity for the aerobic oxidative coupling of amines compared with a molecular catalyst before heterogenization, indicating good prospects for the material with a π-conjugated electronic character. A cross-linked π-conjugated polymeric cobalt phthalocyanine material was prepared, showing high activity for the aerobic oxidative coupling of amines and recyclability.
ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc09422a