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Towards efficient sustainable full-copper dye-sensitized solar cells
Two new heteroleptic copper( i ) sensitizers bearing 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid, to anchor the dye on the titania surface, and a π-delocalized 2-(R-phenyl)-1 H -phenanthro[9,10- d ]imidazole (R = NPh 2 or O-hexyl) ancillary ligand were prepared and well characterized. Their pe...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2019-07, Vol.48 (26), p.973-9711 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c439t-a02f756d523e47ffbacd862d6da732299dbf417efc26bf2f74306ec743d6f12e3 |
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| cites | cdi_FETCH-LOGICAL-c439t-a02f756d523e47ffbacd862d6da732299dbf417efc26bf2f74306ec743d6f12e3 |
| container_end_page | 9711 |
| container_issue | 26 |
| container_start_page | 973 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Dragonetti, Claudia Magni, Mirko Colombo, Alessia Fagnani, Francesco Roberto, Dominique Melchiorre, Fabio Biagini, Paolo Fantacci, Simona |
| description | Two new heteroleptic copper(
i
) sensitizers bearing 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid, to anchor the dye on the titania surface, and a π-delocalized 2-(R-phenyl)-1
H
-phenanthro[9,10-
d
]imidazole (R = NPh
2
or O-hexyl) ancillary ligand were prepared and well characterized. Their performance as dyes in DSSCs is quite similar to that of the related complex bearing 2,9-dimesityl-1,10-phenanthroline as an ancillary ligand, when using the common I
−
/I
3
−
redox couple or homoleptic copper complexes as electron shuttles. The experimental results along with theoretical calculations confirm the great potential of full-copper DSSCs.
Two new heteroleptic copper(
i
) sensitizers with π-delocalized ancillary ligands for full copper DSSCs. |
| doi_str_mv | 10.1039/c9dt00790c |
| format | article |
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i
) sensitizers bearing 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid, to anchor the dye on the titania surface, and a π-delocalized 2-(R-phenyl)-1
H
-phenanthro[9,10-
d
]imidazole (R = NPh
2
or O-hexyl) ancillary ligand were prepared and well characterized. Their performance as dyes in DSSCs is quite similar to that of the related complex bearing 2,9-dimesityl-1,10-phenanthroline as an ancillary ligand, when using the common I
−
/I
3
−
redox couple or homoleptic copper complexes as electron shuttles. The experimental results along with theoretical calculations confirm the great potential of full-copper DSSCs.
Two new heteroleptic copper(
i
) sensitizers with π-delocalized ancillary ligands for full copper DSSCs.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt00790c</identifier><identifier>PMID: 30969290</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Bearing ; Coordination compounds ; Copper ; Copper compounds ; Dye-sensitized solar cells ; Dyes ; Imidazole ; Ligands ; Mass spectra ; NMR ; Nuclear magnetic resonance ; Photovoltaic cells</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019-07, Vol.48 (26), p.973-9711</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-a02f756d523e47ffbacd862d6da732299dbf417efc26bf2f74306ec743d6f12e3</citedby><cites>FETCH-LOGICAL-c439t-a02f756d523e47ffbacd862d6da732299dbf417efc26bf2f74306ec743d6f12e3</cites><orcidid>0000-0001-9776-2973 ; 0000-0001-8004-3200 ; 0000-0002-0106-0860 ; 0000-0001-9659-4760 ; 0000-0002-5478-5216</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30969290$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dragonetti, Claudia</creatorcontrib><creatorcontrib>Magni, Mirko</creatorcontrib><creatorcontrib>Colombo, Alessia</creatorcontrib><creatorcontrib>Fagnani, Francesco</creatorcontrib><creatorcontrib>Roberto, Dominique</creatorcontrib><creatorcontrib>Melchiorre, Fabio</creatorcontrib><creatorcontrib>Biagini, Paolo</creatorcontrib><creatorcontrib>Fantacci, Simona</creatorcontrib><title>Towards efficient sustainable full-copper dye-sensitized solar cells</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Two new heteroleptic copper(
i
) sensitizers bearing 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid, to anchor the dye on the titania surface, and a π-delocalized 2-(R-phenyl)-1
H
-phenanthro[9,10-
d
]imidazole (R = NPh
2
or O-hexyl) ancillary ligand were prepared and well characterized. Their performance as dyes in DSSCs is quite similar to that of the related complex bearing 2,9-dimesityl-1,10-phenanthroline as an ancillary ligand, when using the common I
−
/I
3
−
redox couple or homoleptic copper complexes as electron shuttles. The experimental results along with theoretical calculations confirm the great potential of full-copper DSSCs.
Two new heteroleptic copper(
i
) sensitizers with π-delocalized ancillary ligands for full copper DSSCs.</description><subject>Bearing</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Dye-sensitized solar cells</subject><subject>Dyes</subject><subject>Imidazole</subject><subject>Ligands</subject><subject>Mass spectra</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Photovoltaic cells</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0d9LwzAQB_AgitPpi-9KwRcRqvnRJsujdP6CgS_zuaTJBTq6duZaZP71Zm5O8OkC9-G4-4aQC0bvGBX63mrXU6o0tQfkhGVKpZqL7HD_5nJEThEXlHJOc35MRoJqqbmmJ2Q67z5NcJiA97Wtoe0THLA3dWuqBhI_NE1qu9UKQuLWkCK0WPf1F7gEu8aExELT4Bk58qZBON_VMXl_epwXL-ns7fm1eJilNhO6Tw3lXuXS5VxApryvjHUTyZ10RgnOtXaVz5gCb7msfLSZoBJsLE56xkGMyc127ip0HwNgXy5r3GxgWugGLON5iuUTQUWk1__oohtCG7eLKmdRcT6J6narbOgQA_hyFeqlCeuS0XKTbVno6fwn2yLiq93IoVqC29PfMCO43IKAdt_9-xzxDfB2feo</recordid><startdate>20190702</startdate><enddate>20190702</enddate><creator>Dragonetti, Claudia</creator><creator>Magni, Mirko</creator><creator>Colombo, Alessia</creator><creator>Fagnani, Francesco</creator><creator>Roberto, Dominique</creator><creator>Melchiorre, Fabio</creator><creator>Biagini, Paolo</creator><creator>Fantacci, Simona</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9776-2973</orcidid><orcidid>https://orcid.org/0000-0001-8004-3200</orcidid><orcidid>https://orcid.org/0000-0002-0106-0860</orcidid><orcidid>https://orcid.org/0000-0001-9659-4760</orcidid><orcidid>https://orcid.org/0000-0002-5478-5216</orcidid></search><sort><creationdate>20190702</creationdate><title>Towards efficient sustainable full-copper dye-sensitized solar cells</title><author>Dragonetti, Claudia ; Magni, Mirko ; Colombo, Alessia ; Fagnani, Francesco ; Roberto, Dominique ; Melchiorre, Fabio ; Biagini, Paolo ; Fantacci, Simona</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c439t-a02f756d523e47ffbacd862d6da732299dbf417efc26bf2f74306ec743d6f12e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Bearing</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Dye-sensitized solar cells</topic><topic>Dyes</topic><topic>Imidazole</topic><topic>Ligands</topic><topic>Mass spectra</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Photovoltaic cells</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dragonetti, Claudia</creatorcontrib><creatorcontrib>Magni, Mirko</creatorcontrib><creatorcontrib>Colombo, Alessia</creatorcontrib><creatorcontrib>Fagnani, Francesco</creatorcontrib><creatorcontrib>Roberto, Dominique</creatorcontrib><creatorcontrib>Melchiorre, Fabio</creatorcontrib><creatorcontrib>Biagini, Paolo</creatorcontrib><creatorcontrib>Fantacci, Simona</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dragonetti, Claudia</au><au>Magni, Mirko</au><au>Colombo, Alessia</au><au>Fagnani, Francesco</au><au>Roberto, Dominique</au><au>Melchiorre, Fabio</au><au>Biagini, Paolo</au><au>Fantacci, Simona</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Towards efficient sustainable full-copper dye-sensitized solar cells</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2019-07-02</date><risdate>2019</risdate><volume>48</volume><issue>26</issue><spage>973</spage><epage>9711</epage><pages>973-9711</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Two new heteroleptic copper(
i
) sensitizers bearing 6,6′-dimethyl-2,2′-bipyridine-4,4′-dibenzoic acid, to anchor the dye on the titania surface, and a π-delocalized 2-(R-phenyl)-1
H
-phenanthro[9,10-
d
]imidazole (R = NPh
2
or O-hexyl) ancillary ligand were prepared and well characterized. Their performance as dyes in DSSCs is quite similar to that of the related complex bearing 2,9-dimesityl-1,10-phenanthroline as an ancillary ligand, when using the common I
−
/I
3
−
redox couple or homoleptic copper complexes as electron shuttles. The experimental results along with theoretical calculations confirm the great potential of full-copper DSSCs.
Two new heteroleptic copper(
i
) sensitizers with π-delocalized ancillary ligands for full copper DSSCs.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30969290</pmid><doi>10.1039/c9dt00790c</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-9776-2973</orcidid><orcidid>https://orcid.org/0000-0001-8004-3200</orcidid><orcidid>https://orcid.org/0000-0002-0106-0860</orcidid><orcidid>https://orcid.org/0000-0001-9659-4760</orcidid><orcidid>https://orcid.org/0000-0002-5478-5216</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-07, Vol.48 (26), p.973-9711 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_crossref_primary_10_1039_C9DT00790C |
| source | Royal Society of Chemistry |
| subjects | Bearing Coordination compounds Copper Copper compounds Dye-sensitized solar cells Dyes Imidazole Ligands Mass spectra NMR Nuclear magnetic resonance Photovoltaic cells |
| title | Towards efficient sustainable full-copper dye-sensitized solar cells |
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