Room temperature phosphorescence of Mn() and Zn() coordination polymers for photoelectron response applications

Room temperature phosphorescence of Mn( ii ) and Zn( ii ) based coordination polymers (Mn-CP and Zn-CP) with a different mechanism was confirmed by experiments and theory calculations. The Mn-CP exhibits high photoelectron response performance while Zn-CP can generate frequency tunable alternating c...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2019-08, Vol.48 (29), p.1785-1789
Main Authors: Yang, Xiao-Gang, Zhai, Zhi-Min, Lu, Xiao-Min, Zhao, Ying, Chang, Xin-Hong, Ma, Lu-Fang
Format: Article
Language:English
Subjects:
Coordination polymers
Crystallography
Phosphorescence
Photoelectrons
Polymers
Room temperature
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Summary:Room temperature phosphorescence of Mn( ii ) and Zn( ii ) based coordination polymers (Mn-CP and Zn-CP) with a different mechanism was confirmed by experiments and theory calculations. The Mn-CP exhibits high photoelectron response performance while Zn-CP can generate frequency tunable alternating current when the period of on-off illumination is changed. Mn( ii ) and Zn( ii ) based coordination polymers have been synthesized, which show different mechanism of room temperature phosphorescence and special photoelectron response performance.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt02178g