A fast and simple B-C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts

An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time. This new synthetic methodology provides a new perspective on easy metallacarborane derivatization with organic fragments, which enhances the properties of bot...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2020-03, Vol.49 (11), p.3525-3531
Main Authors: Buades, Ana B, Kelemen, Zsolt, Arderiu, Víctor S, Zaulet, Adnana, Viñas, Clara, Teixidor, Francesc
Format: Article
Language:English
Subjects:
Fragments
Transition metals
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Summary:An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time. This new synthetic methodology provides a new perspective on easy metallacarborane derivatization with organic fragments, which enhances the properties of both fragments and widens their possible applications. An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time.
ISSN:1477-9226
1477-9234
DOI:10.1039/c9dt04695j