Binder-free V 2 O 5 /CNT paper electrode for high rate performance zinc ion battery

• Published in: Nanoscale 2019-10, Vol.11 (42), p.19723-19728
• Main Authors: Yin, Bosi, Zhang, Siwen, Ke, Ke, Xiong, Ting, Wang, Yinming, Lim, Boon Kiang David, Lee, Wee Siang Vincent, Wang, Zhenbo, Xue, Junmin
• Format: Article
• Language: English
• ISSN: 2040-3364; 2040-3372
• DOI: 10.1039/C9NR07458A

Organic compounds, such as polyvinylidene fluoride (PVDF), have been widely used as a binder in battery electrode preparations. While such an approach does not have a significant impact on the performance of the batteries that utilize low valence ions, such as the Li ion battery (LIB), the diffusion of high valence ions (such as Zn 2+ ) will be severely impaired. This will be especially pronounced if the polymeric binder contains highly electronegative atoms, such as fluorine. The high charge density ions, such as Zn 2+ , tend to adsorb onto these electronegative atoms, thus the mobility of these ions across the material is inevitably affected. As such, it becomes highly necessary to consider the binder-free electrode architecture when designing a high rate performing and cycling-stable zinc ion battery (ZIB) cathode. Herein, this work demonstrates an improved Zn ion battery by adopting a freestanding electrode. The obtained V 2 O 5 /CNT paper electrode delivers a specific capacity of 312 mA h g −1 , while achieving a respectable 75% retention in capacity after increasing the current density by 10-fold. Furthermore, excellent cycling stability is recorded with 81% capacity retention after 2000 cycles at 1.0 A g −1 . Thus, this work clearly demonstrated that the freestanding electrode is a promising approach for high valence ion batteries.