2D molecular crystal lattices: advances in their synthesis, characterization, and application

This review identifies how recent advances in controlling the structure and properties of MOF and COF thin films can be used to establish 2D molecular crystals as a new material platform with key applications in catalysis, sensing, separations, and electronics. In addition to summarizing research ef...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2019, Vol.7 (41), p.23537-23562
Main Authors: Solomos, Marina A, Claire, F. James, Kempa, Thomas J
Format: Article
Language:English
Subjects:
Catalysis
Chemical synthesis
Crystal lattices
Crystal structure
Crystals
Thin films
Two dimensional materials
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Summary:This review identifies how recent advances in controlling the structure and properties of MOF and COF thin films can be used to establish 2D molecular crystals as a new material platform with key applications in catalysis, sensing, separations, and electronics. In addition to summarizing research efforts surrounding the synthesis, characterization and utilization of 2D and thin film MOFs and COFs, this review identifies exigent challenges in their development, and motivates the search for new synthetic methods, advanced analytical techniques, and creative applications. Ultimately, 2D molecular lattices, be they 2D MOFs or COFs, are a compelling platform through which to discover new and emergent properties and to expand the library of 2D materials. 2D molecular crystal lattices form a compelling class of 2D materials with synthetically-tunable properties and the potential to spawn a new generation of devices for optoelectronics and energy sustainability.
ISSN:2050-7488
2050-7496
DOI:10.1039/c9ta06534b